10355-01-8

Basic information

• Product Name: Benzene, 1,2-dimethyl-4-(phenylsulfonyl)-
• CAS NO: 10355-01-8
• Molecular Formula: C14H14O2S
• Molecular Weight: 246.33
• Mol File: 10355-01-8.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzene, 1,2-dimethyl-4-(phenylsulfonyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2-dimethyl-4-(phenylsulfonyl)-(10355-01-8)
• EPA Substance Registry System: Benzene, 1,2-dimethyl-4-(phenylsulfonyl)-(10355-01-8)

Safety Data

• Hazardous Substances Data: 10355-01-8(Hazardous Substances Data)

Upstream product

• 31599-61-8 3,4-dimethyliodobenzene 
• 930-69-8 sodium thiophenolate 
• 1019364-34-1 2-(3,4-dimethylphenylthio)aminobenzene 
• 95-47-6 o-xylene 
• 98-11-3 benzenesulfonic acid 
• 71-43-2 benzene 
• 873-55-2 sodium benzenesulfonate 
• 458566-99-9 4,5-dimethyl-2-(trimethylsilyl)phenyl triflate 
• 515-42-4 sodium phenylsulfonate 
• 88-73-3 2-Chloronitrobenzene 
• 96843-22-0 1-bromo-2-chloro-4,5-dimethyl-benzene 
• 18800-53-8 3,4-dimethylthiophenol 
• 98-09-9 benzenesulfonyl chloride 
• 2905-30-8 3,4-dimethylbenzenesulfonyl chloride 

Relevant articles and documents

Rapid and mild sulfonylation of aromatic compounds with sulfonic acids via mixed anhydrides using Tf2O

An efficient and direct sulfonylation of aromatic compounds with sulfonic acids is described via mixed anhydrides in short reaction times using Tf2O in nitromethane at room temperature.

Direct sulfonylation of aromatic rings with aryl or alkyl sulfonic acid using supported P2O5/Al2O3

Direct sulfonylation of aromatic rings with aryl or alkyl sulfonic acid supported P2O5/Al2O3 (w/w 50%) under heterogeneous conditions in short reaction time and high yields. Copyright Taylor & Francis Inc.

The synthesis of diarylsulfones with simple arenes and K2S2O8 through double C-S bond formation

An unprecedented double C-S bond formation method has been developed to prepare both symmetric and unsymmetric diarylsulfones with simple arenes in a single step. This represents the first example that K2S2O8 can be employed as a highly effective sulfonating agent to synthesize diarylsulfones. The reaction demonstrates excellent reactivity, good functional group tolerance and high yields.

Polystyrene supported Al(OTf)3: A stable, efficient, selective, and reusable catalyst for sulfonylation of arenes with sulfonic acids

Cross-linked polystyrene supported aluminium triflate (Ps-Al(OTf) 3) was found to be an efficient and chemoselective heterogeneous Lewis acid catalyst for the direct conversion of arenes to sulfones using sulfonic acids as sulfonylating agents. The solid acid catalyst is stable (as a bench top catalyst) and can be easily recovered and reused without appreciable change in its efficiency.