4670-62-6Relevant articles and documents
Polymerization of Acrylic Acid Esters initiated by Tetrabutylammonium Alkyl- and Aryl-thiolates
Reetz, M. T.,Ostarek, R.
, p. 213 - 215 (1988)
Tetrabutylammonium alkyl- and aryl-thiolates initiate the quantitative polymerization of acrylic acid esters at room temperature to form isotactic polymers having a narrow molecular weight distribution.
Regiospecific reductive elimination from diaryliodonium salts
Wang, Bijia,Graskemper, Joseph W.,Qin, Linlin,DiMagno, Stephen G.
supporting information; experimental part, p. 4079 - 4083 (2010/08/07)
(Figure Presented) Out-of-plane steric bulk furnished by a cyclophane substituent on iodine(III) strongly destabilizes the transition state in the reductive elimination from diaryliodonium salts and leads to regiochemical control (dubbed SECURE), as is demonstrated by computational and experimental studies. This approach should be general for high-valent maingroup and transition metal ions. X=N3, OAc, PhO, CF3CH2O, SCN, PhS.