10364-05-3

Basic information

• Product Name: 1,4-Diiodobicyclo[2.2.2]octane
• Synonyms: 1,4-Diiodobicyclo[2.2.2]octane
• CAS NO: 10364-05-3
• Molecular Formula: C₈H₁₂I₂
• Molecular Weight: 361.9898
• Mol File: 10364-05-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 300.9°Cat760mmHg
• Flash Point: 142.6°C
• Appearance: /
• Density: 2.2g/cm³
• Vapor Pressure: 0.00194mmHg at 25°C
• Refractive Index: 1.662
• CAS DataBase Reference: 1,4-Diiodobicyclo[2.2.2]octane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Diiodobicyclo[2.2.2]octane(10364-05-3)
• EPA Substance Registry System: 1,4-Diiodobicyclo[2.2.2]octane(10364-05-3)

Safety Data

• Hazardous Substances Data: 10364-05-3(Hazardous Substances Data)

Usage

General Description

1,4-Diiodobicyclo[2.2.2]octane is a chemical compound with the formula C8H12I2. It is a bicyclic organic compound that contains two iodine atoms attached to the 1 and 4 positions on the bicyclo[2.2.2]octane ring. 1,4-Diiodobicyclo[2.2.2]octane has a unique three-dimensional structure and is commonly used as a reagent in organic synthesis, particularly in the preparation of complex organic molecules. It is known for its high stability and low reactivity, making it suitable for use in various chemical reactions. Additionally, 1,4-Diiodobicyclo[2.2.2]octane has been studied for its potential pharmaceutical and medicinal applications, particularly in the development of new drugs and therapeutic compounds.

InChI:InChI=1/C8H12I2/c9-7-1-2-8(10,5-3-7)6-4-7/h1-6H2

Upstream product

• 1194-44-1 1,4-dihydroxybicyclo[2.2.2]octane 
• 1123-39-3 1,4-Dichloro-bicyclo<2.2.2>octane 
• 59880-84-1 1,4-Dimethoxy-bicyclo<2.2.2.>octane 
• 711-02-4 1,4-bicyclo[2.2.2]octanedicarboxylic acid 
• 10364-35-9 1,4-Diacetoxybicyclo<2.2.2>octane 
• 54774-94-6 4-acetoxybicyclo<2.2.2>octan-1-ol 
• 10364-04-2 bicyclo[2.2.2]octane-1,4-dibromide 

Downstream Products

• 10364-04-2 bicyclo[2.2.2]octane-1,4-dibromide 
• 74467-53-1 4-(1,1'-Bibicyclo<2.2.2>octyl)yl diphenylcarbinol 
• 74467-52-0 4-(1,1'-Bibicyclo<2.2.2>octyl)yl Phenyl Ketone 
• 74467-38-2 1-Bicyclo<2.2.2>octyl Cyclohexyl Ketone 
• 931-98-6 1-Iodobicyclo<2.2.2>octane 
• 59880-84-1 1,4-Dimethoxy-bicyclo<2.2.2.>octane 
• 74467-18-8 4-Iodo-1-bicyclo<2.2.2>octyl Methyl Ether 

Relevant articles and documents

Molecular Rods: Synthesis and Properties

Our earlier synthetic methodology affording bicyclooctyl -rod and -rod systems proved inadequate for -rods.New synthetic approaches were developed, and - and -rod molecules were obtained.Sodium-potassium coupling was employed to afford the longer rod units.A radical anion approach gave lower yields.Hybrid rods with aromatic rings interposed were also synthesized.Rods of 9.2-, 9.7-, 13.4-, 13.9-, and 18.2-Angstroem length were included in this study.Consideration of rod chirality suggests each bicyclooctane rod unit to be stereogenic, either P (clockwise) or M (anticlockwise).Thus, in a -rod there are enantiomers and in a -rod there are diastereomers.Molecular mechanics treatment of rod stereoisomerization was carried out.Interconversion of enantiomers of the -rod and diastereomers of the -rods should be very rapid at room temperature.X-ray analysis of the 4,4'-dimethoxy--rod reveals an achiral conformation.AM1 quantum mechanics computations were carried out on -rod radical cations and bridgehead cations.

Rod-Like Organic Molecules. Energy-Transfer Studies Using Single-Photon Counting

The synthesis of rod-like molecules was devised wherein the rods were composed of bicyclooctane units bonded bridgehead to bridgehead.Various end chromophores were placed at the terminal bridgehead sites of -rods and -rods, these being consti