10364-68-8Relevant academic research and scientific papers
Imidazole hydrochloride promoted synthesis of 3,5-disubstituted-1,2,4-oxadiazoles
Wang, Xuetong,Wang, Yin,Liu, Xiaoling,He, Tingshu,Li, Lingli,Wu, Huili,Zhou, Shangjun,Li, Dan,Liao, Siwei,Xu, Ping,Huang, Xing,Yuan, Jianyong
supporting information, (2021/10/14)
Imidazole hydrochloride as an additive promotes the reaction of amidoximes and DMA derivatives to generated 3,5-disubstituted-1,2,4-oxadiazoles in low to excellent yields without the use of coupling reagents, oxidants, strong acids or bases and other additives.
Efficient insecticidal aerosol and preparation method thereof
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Paragraph 0058; 0069-0071; 0076-0077, (2020/10/30)
The invention provides an efficient insecticidal aerosol, which comprises the following components in percentage by weight: 0.1-0.5wt% of a component A, i.e. a 1, 2, 4-diazole derivative shown as a formula I, 1-1.5wt% of a component B, i.e. a marigold ext
One-pot synthesis of 1,2,4-oxadiazoles from carboxylic acids using 4-(dimethylamino)pyridinium acetate as efficient, regenerable, and green catalyst with ionic liquid character
Nowrouzi, Najmeh,Khalili, Dariush,Irajzadeh, Maryam
, p. 801 - 806 (2015/03/18)
A recyclable bifunctional acid-base organocatalyst with ionic liquid character has been prepared and its catalytic activity for the preparation of oxadiazoles has been investigated.
Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent
Yoshimura, Akira,Nguyen, Khiem C.,Klasen, Scott C.,Saito, Akio,Nemykin, Victor N.,Zhdankin, Viktor V.
supporting information, p. 7835 - 7838 (2015/05/13)
A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is
Efficient and convenient protocol for the synthesis of 3,5-disubstituted 1,2,4-oxadiazoles using HClO4-SiO2 as a heterogeneous recyclable catalyst
Tadikonda, Ramu,Nakka, Mangarao,Gajula, Mahaboob Basha,Rayavarapu, Srinuvasarao,Gollamudi, Padma Rao,Vidavalur, Siddaiah
supporting information, p. 1978 - 1986 (2014/07/07)
Silica-supported perchloric acid (HClO4SiO2) was found to be a new, highly efficient, inexpensive, and reusable catalyst for a rapid and efficient synthesis of various 1,2,4-oxadiazoles with good to excellent yields under solvent-free conditions. The present methodology has been effectively utilized for the synthesis of oxolamine, an anti-inflammatory drug.
Br?nsted acid-catalyzed simple and efficient synthesis of 1,2,4-triazoles and 1,2,4-oxadiazoles using 2,2,2-trichloroethyl imidates in PEG
Mangarao, Nakka,Mahaboob Basha, Gajula,Ramu, Tadikonda,Srinuvasarao, Rayavarapu,Prasanthi, Sarakula,Siddaiah, Vidavalur
supporting information, p. 177 - 179 (2014/01/06)
A facile and highly efficient synthesis of 3,4,5-trisubstituted 1,2,4-triazoles and 3,5-disubstituted 1,2,4-oxadiazoles from 2,2,2-trichloroethyl imidates using PEG as a solvent and employing PTSA as the catalyst under mild conditions is described.
A novel, one-pot, three-component synthesis of 1,2,4-oxadiazoles under microwave irradiation and solvent-free conditions
Adib, Mehdi,Mahdavi, Mohammad,Mahmoodi, Niusha,Pirelahi, Hooshang,Bijanzadeh, Hamid Reza
, p. 1765 - 1767 (2008/02/04)
A novel synthesis of 3,5-disubstituted 1,2,4-oxadiazoles is described from a one-pot, three-component reaction between nitriles, hydroxylamine, and Meldrum's acids under microwave irradiation and solvent-free conditions in good to excellent yields. Georg
Electrochemical oxidation of substituted amide oximes and 4,5-dihydro-1,2,4-oxadiazoles
Okimoto, Mitsuhiro,Takahashi, Yukio
, p. 427 - 428 (2007/10/03)
The electrooxidation of several substituted amide oximes to yield the corresponding nitriles, alcohols, and imidate was successfully carried out. The reaction products were dependent on the substituents. Additionally, 4,5-dihydro-1,2,4-oxadiazoles derived from amide oximes were electro-oxidized to afford 1,2,4-oxadiazoles in good yields.
A Simplified Procedure for Preparing 3,5-Disubstituted-1,2,4-Oxadiazoles by Reaction of Amidoximes with Acyl Chlorides in Pyridine Solution
Chiou, Shishue,Shine, Henry J.
, p. 125 - 128 (2007/10/02)
3-R-5-R'-1,2,4-Oxadiazoles are prepared in fair to good yield by short-time, one-pot reaction of an amidoxime, RC(NH2)NOH, with an acyl chloride, R'COCl, in pyridine solution.Precipitation of the oxadiazole occurs on diluting the pyridine reaction solutio
