103655-02-3

Upstream product

• 354-58-5 1,1,1-Trichloro-2,2,2-trifluoroethane 
• 123-11-5 4-methoxy-benzaldehyde 
• 13710-18-4 C₂Cl₃F₃Zn 
• 306-83-2 1,1,1-trifluoro-2,2-dichloroethane 

Downstream Products

• 131510-34-4 1-(2,2-Dichloro-1,3,3,3-tetrafluoro-propyl)-4-methoxy-benzene 
• 118968-67-5 1-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-4-methoxybenzene 
• 82203-83-6 1-(p-methoxyphenyl)-3,3,3-trifluoropropyne 
• 122247-05-6 3-(4-Chloro-phenyl)-5-(4-methoxy-phenyl)-4-trifluoromethyl-isoxazole 
• 122247-15-8 3-(2,6-Dichloro-phenyl)-4-(4-methoxy-phenyl)-5-trifluoromethyl-isoxazole 
• 122247-08-9 3-(2,6-Dichloro-phenyl)-5-(4-methoxy-phenyl)-4-trifluoromethyl-isoxazole 
• 131510-45-7 1-((Z)-2-Chloro-1,3,3,3-tetrafluoro-propenyl)-4-methoxy-benzene 
• 131510-45-7 1-((E)-2-Chloro-1,3,3,3-tetrafluoro-propenyl)-4-methoxy-benzene 
• 155270-05-6 C₁₀H₇Cl₂F₃O₂ 

Relevant academic research and scientific papers

Direct electroreduction or use of an electrogenerated base : Two ways for the coupling of polyhalogenated compounds with aldehydes or ketones

The electrochemical coupling of polyhalogenated compounds with carbonyl compounds is achieved in two ways. A carbanion RX(n)- is generated either by the direct electroreduction of RX(n)Cl or by deprotonation of RX(n)H. In this latter case the base Ph- is electrogenerated by reduction of iodobenzene. All electrolysis were carried out in an undivided cell fitted with a cadmium-coated cathode and an aluminium or magnesium sacrificial anode.

A Facile Stereoselcetive Synthesis of (E)-1-Aryl-1,2,3,3,3-pentafluoropropenes and (E)-1-Aryl-2-chloro-1,3,3,3-tetrafluoropropenes

Arenecarbaldehydes ArCHO were allowed to react with a carbenoid reagent CF3CX2Mtl (X=Cl, Mtl=ZnCl, X=F, Mtl=LI) to give the adducts ArCH(OH)CX2CF3 whose hydroxyl group was substituted by fluorine.Dehydrohalogenating of the resultant ArCHFCX2CF3 (X=Cl or F

PbBr2/Al-Promoted Reductive Addition of 1,1,1-trichloro-2,2,2-trifluoroethane (Flon) to Aldehydes

Introduction of CF3CCl2 unit into aldehydes with CF3CCl3 has been perfomed successfully by the action of catalytic PbBr2 and Al foils in DMF.