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1036637-32-7

methyl (1S,2R)-1-nitro-2-phenylcyclopropanecarboxylate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1036637-32-7 Structure

  • Basic information

    1. Product Name: methyl (1S,2R)-1-nitro-2-phenylcyclopropanecarboxylate
    2. Synonyms: methyl (1S,2R)-1-nitro-2-phenylcyclopropanecarboxylate
    3. CAS NO:1036637-32-7
    4. Molecular Formula:
    5. Molecular Weight: 221.213
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1036637-32-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: methyl (1S,2R)-1-nitro-2-phenylcyclopropanecarboxylate(CAS DataBase Reference)
    10. NIST Chemistry Reference: methyl (1S,2R)-1-nitro-2-phenylcyclopropanecarboxylate(1036637-32-7)
    11. EPA Substance Registry System: methyl (1S,2R)-1-nitro-2-phenylcyclopropanecarboxylate(1036637-32-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1036637-32-7(Hazardous Substances Data)

1036637-32-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1036637-32-7 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,3,6,6,3 and 7 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1036637-32:
(9*1)+(8*0)+(7*3)+(6*6)+(5*6)+(4*3)+(3*7)+(2*3)+(1*2)=137
137 % 10 = 7
So 1036637-32-7 is a valid CAS Registry Number.

1036637-32-7Relevant articles and documents

Catalytic asymmetric synthesis of nitrocyclopropane carboxylates

Moreau, Benoit,Alberico, Dino,Lindsay, Vincent N.G.,Charette, Andre B.

experimental part, p. 3487 - 3496 (2012/06/04)

A Cu(I)-catalyzed asymmetric cyclopropanation of alkenes with an iodonium ylide has been developed. The copper source, hypervalent iodine source, solvent, and additives all have a significant effect on the yields and enantioselectivities. High enantioselectivity (up to 99:1 er) and diastereoselectivity (95:5 dr trans/cis) were achieved for a wide range of alkenes. Conditions were developed to convert the trans products to the cis isomers. In addition, 1-nitrocyclopropyl carboxylates were transformed into the corresponding substituted cyclopropane amino acids and aminocyclopropanes. Moreover, a comparative study between Zn- and In-mediated reduction reactions of the nitro group in these compounds with regards to the er erosion in the process is also documented.

Expedient synthesis of cyclopropane α-amino acids by the catalytic asymmetric cyclopropanation of alkenes using iodonium ylides derived from methyl nitroacetate

Moreau, Benoit,Charette, Andre B.

, p. 18014 - 18015 (2007/10/03)

A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and methyl nitroacetate is reported. The cyclopropanation took place with high enantioselectivity for a wide range of alkenes, and the reaction was performed at room temperature. 1-Nitrocyclopropyl esters are versatile building blocks to access the corresponding cyclopropane amino esters and aminocyclopropanes in two and three steps, respectively, from commercially available products. Copyright

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