10368-73-7

Basic information

• Product Name: 2-BroMo-1,3,5-triphenylbenzene
• Synonyms: 2-BroMo-1,3,5-triphenylbenzene;1-broMo-2,4,6-triphenylbenzene;2'-Bromo-5'-phenyl-1,1':3',1''-terphenyl;2,4,6-Triphenylbromobenzene
• CAS NO: 10368-73-7
• Molecular Formula: C₂₄H₁₇Br
• Molecular Weight: 385.29578
• Mol File: 10368-73-7.mol
• Article Data: 6

Chemical Properties

• Melting Point: 128.0 to 132.0 °C
• Boiling Point: 479.7°C at 760 mmHg
• Flash Point: 235.5°C
• Appearance: /
• Density: 1.278g/cm³
• Vapor Pressure: 6.74E-09mmHg at 25°C
• Refractive Index: 1.633
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2-BroMo-1,3,5-triphenylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BroMo-1,3,5-triphenylbenzene(10368-73-7)
• EPA Substance Registry System: 2-BroMo-1,3,5-triphenylbenzene(10368-73-7)

Safety Data

• Hazardous Substances Data: 10368-73-7(Hazardous Substances Data)

Usage

General Description

2-Bromo-1,3,5-triphenylbenzene is a chemical compound consisting of a benzene ring with three phenyl groups attached, and a bromine atom attached at the 2 position. It is a white crystalline solid that is used in organic synthesis and as a building block for more complex molecules. 2-BroMo-1,3,5-triphenylbenzene has potential applications in materials science and pharmaceutical research due to its unique structure and reactivity. It is important to handle and store 2-Bromo-1,3,5-triphenylbenzene with care, as it can be harmful if ingested or inhaled, and can cause irritation to the skin and eyes upon contact.

InChI:InChI=1/C24H17Br/c25-24-22(19-12-6-2-7-13-19)16-21(18-10-4-1-5-11-18)17-23(24)20-14-8-3-9-15-20/h1-17H

Upstream product

• 75-15-0 carbon disulfide 
• 612-71-5 1,3,5-triphenylbenzene 
• 7726-95-6 bromine 

Downstream Products

• 604-53-5 1,1'-bisnaphthalene 
• 612-71-5 1,3,5-triphenylbenzene 
• 1430802-60-0 9,9-bis(phenyldimethylsilyl)-1,3-diphenyl-9-silafluorene 
• 198885-80-2 9,9-bis(trimethylsilyl)-1,3-diphenyl-9-silafluorene 
• 1430802-59-7 1,3,9,9-tetraphenyl-9-silafluorene 
• 1430802-58-6 1,1′,3,3′-tetraphenyl-9-silaspirofluorene 
• 1430802-57-5 9,9-dichloro-1,3-diphenyl-9-silafluorene 
• 1284281-06-6 5-mesityl-1,9-bis(2,4,6-triphenylphenyl)dipyrromethene 
• 1284281-05-5 5-mesityl-1,9-di(2,4,6-triphenylphenyl)dipyrromethane 
• 1184955-08-5 bis-[2,6-(2,4,6-triphenyphenyl)]pyridine 
• 74-85-1 ethene 
• 64723-93-9 acetaldehyde enolate 

Relevant articles and documents

Alkali metal-stabilized 1,3,5-triphenylbenzene monoanions: Synthesis and characterization of the lithium, sodium, and potassium complexes

Alkali metal stabilized monoanions of 1,3,5-triphenylbenzene can be obtained by various reactions starting from the alkali metal. Reduction of the Grignard compound [{(2,4,6-Ph3-C6H2)Mg(dme)Br} 2(μ-O,O′-dme)] (3

Mechanistic elucidation of the formation of the inverse Ca(I) sandwich complex [(thf)3Ca(μ-C6H3-1,3,5-Ph 3)Ca(thf)3] and stability of aryl-substituted phenylcalcium complexes

The formation of the stable inverse Ca(I) sandwich complex [(thf) 3Ca(μ-C6H3-1,3,5-Ph3)Ca(thf) 3] (1) has been investigated mechanistically by the reaction of bromo-2,4,6-triphenylbenzene with calcium

The AZARYPHOS family of ligands for ambifunctional catalysis: Syntheses and use in ruthenium-catalyzed anti-markovnikov hydration of terminal alkynes

The family of AZARYPHOS (aza-aryl-phosphane) phosphane ligands, containing a phosphine unit and sterically shielded nitrogen lone pairs in the ligand periphery, is introduced as a tool for developing ambifunctional catalysis by the metal center and nitrogen lone pairs in the ligand sphere. General synthetic strategies have been developed to synthesize over 25 examples of structurally diverse (6-aryl-2pyridyl)phosphanes (ARPYPHOS), (6alkyl-2-pyridyl)phosphanes (ALPY-PHOS), 4,6-disubsituted l,3-diazin-2ylphosphanes or l,3,5-triazin-2- ylphosphanes, quinazolinylphosphanes, quinolinylphosphanes, and others. The scalable syntheses proceed in a few steps. The incorporation of AZARYPHOS ligands (L) into complexes [RuCp(L)2(MeCN)][PF6] (Cp = cyclopentadieny1)gives catalysts for the anti-Markovnikov hydration of terminal alkynes of the highest known activities. Electronic and steric ligand effects modulate the reaction kinetics over a range of two orders of magnitude. These results highlight the importance of using structurally diverse ligand families in the process of developing cooperative ambifunctional catalysis by a metal and its ligand.