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10375-34-5

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10375-34-5 Usage

Uses

2,5-Furandicarbonyl Dichloride is used as a modifier in wood.

Check Digit Verification of cas no

The CAS Registry Mumber 10375-34-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,3,7 and 5 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 10375-34:
(7*1)+(6*0)+(5*3)+(4*7)+(3*5)+(2*3)+(1*4)=75
75 % 10 = 5
So 10375-34-5 is a valid CAS Registry Number.

10375-34-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name furan-2,5-dicarbonyl chloride

1.2 Other means of identification

Product number -
Other names 2,5-Furandicarboxylic acid chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10375-34-5 SDS

10375-34-5Downstream Products

10375-34-5Relevant articles and documents

Small-scale screening of novel biobased monomers: the curious case of 1,3-cyclopentanediol

Noordzij,Dietz,Leoné,Wilsens,Rastogi

, p. 39818 - 39828 (2018)

In this work, we report on the small scale polycondensation and consecutive analysis of novel polyesters based on the potentially renewable 1,3-cyclopentanediol (CPdiol). To avoid evaporation of monomers during thin-film polymerization reactions, trimer pre-polyesters have been synthesized from the corresponding acid-chlorides with diol monomers. Polymerization of these trimers was explored by thermogravimetric analysis to identify potential side reactions, and to assess the ideal polymerization temperature. In general we observe that trans-1,3-cyclopentanediol exhibits good thermal stability up to 200 °C, whereas thermal dehydration of the alcohol end-groups occurs upon further heating. In contrast, for cis-1,3-cyclopentanediol, the ester bonds of the cyclopentane end-groups become labile, thereby generating carboxylic acid end-groups, and 3-cyclopentenol already at 180 °C. The thermal dehydration reactions yield double bond end-groups, which in turn facilitate cross-linking through cross-coupling and Diels-Alder reactions, leading to an increase in molecular weight. Despite the limited thermal stability of CPdiol, here we demonstrate that polymerization of CPdiol can successfully be achieved in thin-film polycondensation conditions at 180 °C, yielding molecular weights well above 10 kg mol?1.

Novel diamidino-substituted derivatives of phenyl benzothiazolyl and dibenzothiazolyl furans and thiophenes: Synthesis, antiproliferative and DNA binding properties

Racané, Livio,Trali?-Kulenovi?, Vesna,Paveli?, Sandra Kraljevi?,Ratkaj, Ivana,Peixoto, Paul,Nhili, Raja,Depauw, Sabine,Hildebrand, Marie-Paule,David-Cordonnier, Marie-Hélène,Paveli?, Kre?imir,Karminski-Zamola, Grace

, p. 2418 - 2432 (2010)

A series of new diamidino-, diisopropylamidino-, and diimidazolinyl- substituted derivatives of phenyl benzothiazolyl and dibenzothiazolyl furans and thiophenes were successfully prepared and evaluated for their antiproliferative activity on tumor cell lines in vitro, DNA binding propensity, and sequence selectivity as well as cellular distribution. A strong antiproliferative effect of the tested compounds was observed on all tested cell lines in a concentration-dependent response pattern. In general, imidazolinyl-substituted derivatives and/or the thiophene core were in correlation with increased antiproliferative activity. Two compounds (2b and 3b) were chosen for biological studies due to their differential antiproliferative properties. The DNA binding properties of this new series of compounds were assessed and evidenced their efficient minor groove binding properties with preferential interaction at AT-rich sites. Both compounds also present nuclear subcellular localization, suggesting that their cellular mode of action implies localization in the DNA compartment and direct inhibition of DNA replication and induction of apoptosis.

Benzene-, pyrrole-, and furan-containing diametrically strapped calix[4]pyrroles - An experimental and theoretical study of hydrogen-bonding effects in chloride anion recognition

Yoon, Dae-Wi,Gross, Dustin E.,Lynch, Vincent M.,Sessler, Jonathan L.,Hay, Benjamin P.,Lee, Chang-Hee

, p. 5038 - 5042 (2008)

(Figure Presented). Weak but important: The chloride anion binding properties of diametrically strapped calixpyrroles bearing benzene (see structure), pyrrole, and furan moieties in the strap have been studied in the solid state, in solution, and through theoretical analyses. The results obtained provide support for the notion that C-H...Cl- hydrogen bonds are significant and contribute substantially to the Cl- binding energetics.

Production of 5-(chloromethyl)furan-2-carbonyl chloride and furan-2,5-dicarbonyl chloride from biomass-derived 5-(chloromethyl)furfural (CMF)

Dutta, Saikat,Wu, Linglin,Mascal, Mark

, p. 3737 - 3739 (2015)

Acid chloride derivatives of 5-(chloromethyl)furan-2-carboxylic acid and furan-2,5-dicarboxylic acid (FDCA) can be produced in high yield by treatment of the precursor aldehydes 5-(chloromethyl) furfural (CMF) and 2,5-diformylfuran (DFF) with tert-butyl hypochlorite, which is inexpensively prepared from commercial bleach and tert-butanol. 5-(Chloromethyl)furan-2-carbonyl chloride (CMFCC) and furan-2,5-dicarbonyl chloride (FDCC) are highly useful intermediates for the production of furoate ester biofuels and polymers of FDCA.

Synthesis of fluorine-containing esters of 2,5-furandicarboxylic acid

Sakharov,Smirnova,Glazkov,Yarosh

, p. 1899 - 1902 (2018)

Fluorinated esters of 2,5-furandicarboxylic acid have been synthesized starting from 2,5-furan dicarboxylic acid dichloride and fluorine-containing diols. The reaction control was performed by means of 1H, 19F NMR, and IR-spectroscopy. Thermal stability, as well as glass transition temperature, and intrinsic viscosity parameters of the obtained oligomers have been determined.

Selective recovery of rare earth elements using chelating ligands grafted on mesoporous surfaces

Florek, Justyna,Mushtaq, Ambreen,Larivière, Dominic,Cantin, Gabrielle,Fontaine, Frédéric-Georges,Kleitz, Freddy

, p. 103782 - 103789 (2015)

Nowadays, rare earth elements (REEs) and their compounds are critical for the rapidly growing advanced technology sectors and clean energy demands. However, their separation and purification still remain challenging. Among different extracting agents used for REE separation, the diglycolamide (DGA)-based materials have attracted increasing attention as one of the most effective extracting agents. In this contribution, a series of new and element-selective sorbents were generated through derivatisation of the diglycolamide ligand (DGA), grafted to mesoporous silica and tested for the separation of rare earth elements. It is shown that, by tuning the ligand bite angle and its environment, it is possible to improve the selectivity towards specific rare earth elements.

Novel methylselenoesters induce programed cell death via entosis in pancreatic cancer cells

Khalkar, Prajakta,Díaz-Argelich, Nuria,Palop, Juan Antonio,Sanmartín, Carmen,Fernandes, Aristi P.

, (2018)

Redox active selenium (Se) compounds have gained substantial attention in the last decade as potential cancer therapeutic agents. Several Se compounds have shown high selectivity and sensitivity against malignant cells. The cytotoxic effects are exerted by their biologically active metabolites, with methylselenol (CH3SeH) being one of the key executors. In search of novel CH3SeH precursors, we previously synthesized a series of methylselenoesters that were active (GI50 3SeH precursors induced entosis by cell detachment through downregulation of cell division control protein 42 homolog (CDC42) and its downstream effector β1-integrin (CD29). To our knowledge, this is the first time that Se compounds have been reported to induce this type of cell death and is of importance in the characterization of the anticancerogenic properties of these compounds.

Method for preparing 2, 5-furandicarbonyl chloride from 5-chloromethylfurfural

-

Paragraph 0009; 0029-0106, (2021/04/10)

The invention discloses a method for preparing 2, 5-furan diformyl chloride from 5-chloromethyl furfural, and relates to the technical field of organic synthesis, wherein the 2, 5-furan diformyl chloride can be obtained by one-step reaction of 5-chloromethyl furfural under the action of a catalyst, a cocatalyst and an organic solvent. The 5-chloromethylfurfural used in the invention is commercialized, and can be directly prepared into the 5-chloromethylfurfural by deep hydrolysis of biomass, so the invention provides a sustainable development approach for preparing the 2, 5-furandicarboxylic acid dichloride by using renewable resources; and a metal organic framework material catalyst and a cocatalyst are adopted to convert the 5-chloromethyl furfural into the 2, 5-furan diformyl chloride with high selectivity through one-step reaction, and the reaction condition is mild and the yield is high.

Method for preparing 2,5-furandicarbonyldichloride from furan-2,5-dicarbaldehyde

-

Paragraph 0032-0111, (2019/08/31)

The application discloses a method for preparing 2,5-furandicarbonyldichloride from furan-2,5-dicarbaldehyde. Specifically the method comprises the following steps: adding an organic solvent and trichloroisocyanuric acid at 15-80 DEG C, and converting furan-2,5-dicarbaldehyde to 2,5-furandicarbonyldichloride under the catalysis of 2,2,6,6-tetramethylpiperidinooxy by the one pot method. According to the method, the raw material source is wide, the product yield is high, the process route is simple, and thus the method has potential industrial application prospects.

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