103844-15-1

Basic information

• Product Name: 1,3-Benzodioxole, 5-[(phenylthio)methyl]-
• CAS NO: 103844-15-1
• Molecular Formula: C14H12O2S
• Molecular Weight: 244.314
• Mol File: 103844-15-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1,3-Benzodioxole, 5-[(phenylthio)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Benzodioxole, 5-[(phenylthio)methyl]-(103844-15-1)
• EPA Substance Registry System: 1,3-Benzodioxole, 5-[(phenylthio)methyl]-(103844-15-1)

Safety Data

• Hazardous Substances Data: 103844-15-1(Hazardous Substances Data)

Upstream product

• 20850-43-5 5-(chloromethyl)-1,3-benzodioxole 
• 108-98-5 thiophenol 
• 495-76-1 piperonol 
• 882-33-7 diphenyldisulfane 
• 7145-99-5 5-methyl-1,3-benzodioxole 
• 120-57-0 piperonal 
• 2606-51-1 3,4-Methylenedioxybenzyl bromide 
• 86633-25-2 benzo[d][1,3]dioxol-5-ylmethyl methyl ether 

Downstream Products

• 129819-59-6 N-2-(2-furylethyl) α-phenylthio-1,3-benzodioxole-5-ethanamine 
• 129819-55-2 N-3,5-hexadienyl α-phenylthio-1,3-benzodioxole-5-ethanamine 
• 129819-62-1 (2-Benzo[1,3]dioxol-5-yl-2-phenylsulfanyl-ethyl)-(2-furan-2-yl-ethyl)-carbamic acid ethyl ester 
• 129819-56-3 (2-Benzo[1,3]dioxol-5-yl-2-phenylsulfanyl-ethyl)-((E)-hexa-3,5-dienyl)-carbamic acid ethyl ester 
• 103844-20-8 3-hydroxymethyl-5,6,7-trimethoxy-4-(3',4'-methylenedioxyphenyl)-1α-phenylthio-1,2,3,4-tetrahydro-2-naphthoic acid γ-lactone 
• 17187-78-9 rac-(7'β,8β,8'α)-7-hydroxy-3',4',5'-trimethoxy-3,4-methylenedioxylignan-9',9-olides 
• 103844-20-8 3-hydroxymethyl-5,6,7-trimethoxy-4-(3',4'-methylenedioxyphenyl)-1β-phenylthio-1,2,3,4-tetrahydro-2-naphthoic acid γ-lactone 
• 103844-21-9 3-hydroxymethyl-6,7-methylenedioxy-4-phenylthio-1-(3',4',5'-trimethoxyphenyl)-1,2,3,4-tetrahydro-2-naphthoic acid γ-lactone 
• 477-51-0 rac-(7'β,8α,8'percentb)-3',4',5'-trimethoxy-4,5-methylenedioxy-2,7'-cyclolignan-9',9-olide 
• 126798-87-6 α-phenylthio-1,3-benzodioxoleacetaldehyde 
• 103844-17-3 2-(α-hydroxy-3',4',5'-trimethoxybenzyl)-3-(3'',4''-methylenedioxy-α-phenylthiobenzyl)-γ-butyrolactone 

Relevant articles and documents

Indium(I) iodide-promoted cleavage of diaryl diselenides and disulfides and subsequent condensation with alkyl or acyl halides. One-pot efficient synthesis of diorganyl selenides, sulfides, selenoesters, and thioesters

Diphenyl diselenides and disulfides undergo facile cleavages by indium(I) iodide and the corresponding generated selenate and thiolate anions condense in situ with alkyl or acyl halides present in the reaction mixture. Thus, a simple, efficient, and general procedure has been developed for the synthesis of unsymmetrical diorganyl selenides, sulfides (thioethers), selenoesters, and thioesters by this one-pot reaction at room temperature.

Preparation method of alkyl sulfide

The invention relates to a preparation method of alkyl sulfide. The method comprises the following steps: under the protection of nitrogen, sequentially adding transition metal, a nitrogen ligand, a cocatalyst, an oxidant, a solvent, alkane and thiophenol or mercaptan into a reaction tube, carrying out oxidative dehydrogenation coupling reaction at 80-150 DEG C, ending the reaction after 6-48 hours, evaporating the solvent to dryness, and carrying out column chromatography separation to obtain the alkyl sulfide compound. The method is simple in synthesis process, mild in reaction condition, high in yield and easy to industrialize.

Visible-Light-Induced Cyclization of Electron-Enriched Phenyl Benzyl Sulfides: Synthesis of Tetrahydrofurans and Tetrahydropyrans

A new approach to the preparation of tetrahydrofurans and tetrahydropyrans through a photoredox catalytic process is described. The introduction of a phenylsulfanyl auxiliary group permits the substrates to be readily oxidized to form cationic intermediates for sequential intramolecular cyclization. The method features mild reaction conditions and operational simplicity.