103884-34-0Relevant articles and documents
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Caputo,R. et al.
, p. 963 - 967 (1974)
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PROCESS FOR MAKING FORMIC ACID UTILIZING LOWER-BOILING FORMATE ESTERS
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Paragraph 00177; 00178, (2019/02/15)
Disclosed is a process for recovering formic acid from a formate ester of a C3 to C4 alcohol. Disclosed is also a process for producing formic acid by carbonylating a C3 to C4 alcohol, hydrolyzing the formate ester of the alcohol, and recovering a formic acid product. The alcohol may be dried and returned to the reactor. The process enables a more energy efficient production of formic acid than the carbonylation of methanol to produce methyl formate.
Phase-Managed Organic Synthesis. A New Synthesis of Mixed Formic Anhydrides
Fife, Wilmer K.,Zhang, Zhi-dong
, p. 3744 - 3746 (2007/10/02)
Two new mixed formic anhydrides, cinnamic formic anhydride and formic 4-methoxybenzoic anhydride, can be prepared in high yield ( c.a. 80percent) from equimolar mixtures of sodium formate and the appropriate acid chloride with a solid-phase copolymer of pyridine 1-oxide as catalyst, and they exhibit excellent selectivity as formylating agents of alcohols and amines