1039357-66-8Relevant articles and documents
A chemoenzymatic synthesis of hept-6-ene-2,5-diol stereomers: Application to asymmetric synthesis of decarestrictine L, pyrenophorol, and stagonolide e
Chatterjee, Sucheta,Ghadigaonkar, Sneha,Sur, Payel,Sharma, Anubha,Chattopadhyay, Subrata
, p. 8067 - 8076 (2015/03/18)
The stereomers of hept-6-ene-2,5-diol derivatives were conceived as useful chiral intermediates and were synthesized starting from sulcatol using two lipase-catalyzed acylation reactions as the key steps. The versatility of the intermediates was demonstrated by converting them to the titled tetrahydropyran, macrolide, and macrodiolide compounds using standard synthetic protocols.