10437-24-8

Basic information

• Product Name: 3β-formyloxy-5αH-cholestane
• Synonyms: 3β-formyloxy-5αH-cholestane
• CAS NO: 10437-24-8
• Molecular Weight: 416.688
• Mol File: 10437-24-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3β-formyloxy-5αH-cholestane(CAS DataBase Reference)
• NIST Chemistry Reference: 3β-formyloxy-5αH-cholestane(10437-24-8)
• EPA Substance Registry System: 3β-formyloxy-5αH-cholestane(10437-24-8)

Safety Data

• Hazardous Substances Data: 10437-24-8(Hazardous Substances Data)

Upstream product

• 84551-47-3 N-methyl N-phenyl carbamate de cholestanyle-3β 
• 110-83-8 cyclohexene 
• 92216-61-0 N-(5α-cholestan-3β-yloxythiocarbonyl)-N,N-dimethylamine 
• 121569-78-6 Methyl-phenyl-carbamic acid (3S,5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yl ester 
• 121569-79-7 Phenyl-thiocarbamic acid O-[(3S,5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yl] ester 
• 95782-88-0 3β-phenylcarbamoyloxy-5α-cholestane 
• 79-37-8 oxalyl dichloride 
• 80-97-7 Cholestanol 

Downstream Products

• 64-18-6 formic acid 
• 481-21-0 cholestane 
• 80-97-7 Cholestanol 

Relevant articles and documents

Reduction et photoreduction de derives de l'acide carbonique influence de l'hexamethylphosphorotriamide

Photoreduction and reduction of carbonic acid derivatives in HMPT have been compared.The highest yield of alkane was obtained from N,N-dimethylthiocarbamates either by the photochemical method or by reduction with a dissolved metal.Competitive reactions have been characterized: - during the photoreduction not only the alkane but products of a photo-Fries rearrangement and products of a homolytic cleavage were detected; - basic reactions can compete with the reduction of carbonic acid derivatives by sodium in HMPT.

PHOTOREACTIVITE DE DERIVES DE L'ACIDE CARBONIQUE EN MILIEU REDUCTEUR

Photoreduction of carbamates, thiocarbamates and carbonate occurs in a mixture of HMPT-H2O.A better yield of alkane is observed for thiocarbamates.Formates and photoFries products are also isolated from the reaction mixture.Radical intermediates can be trapped by cyclohexene even in HMPA.