104470-29-3Relevant academic research and scientific papers
HIGHLY SELECTIVE γ-ALKYLATION OF TRIISOPROPYLSILYLALLYL ANION. SYNTHESIS OF α-TRIISOPROPYLSILYL ALDEHYDES.
Muchowski, Joseph M.,Naef, Reto,Maddox, Michael L.
, p. 5375 - 5378 (1985)
The reaction of triisopropylsilylallyllithium with alkyl halides took place with considerably greater γ-selectivity than reported for trimethylsilyl allyllithium.Silica gel induced rearrangement of the epoxides 5 derived from the alkylation products 3 gave α-triisopropylsilyl aldehydes 6 by a process in which silyl group transposition occurred with predominant inversion at the migration terminus.
