24400-84-8 Usage
Description
ALLYLTRIISOPROPYLSILANE, an organic compound with a distinctive strong odor, is a colorless, flammable liquid. It features a chemical structure where an allyl group is attached to a silicon atom, complemented by three isopropyl groups. ALLYLTRIISOPROPYLSILANE is renowned for its versatility in organic chemistry, enabling a range of chemical reactions, and is particularly recognized for its role as a protecting group in the synthesis of various organic compounds and in the preparation of silicon-containing polymers and materials.
Uses
Used in Organic Synthesis:
ALLYLTRIISOPROPYLSILANE is used as a reagent for its ability to participate in a variety of chemical reactions, facilitating the synthesis of different organic compounds.
Used in the Protection of Functional Groups:
In the realm of organic chemistry, ALLYLTRIISOPROPYLSILANE serves as a protecting group, particularly for alcohols and amines, safeguarding these functional groups during chemical reactions where they might otherwise be reactive.
Used in the Preparation of Polymers and Materials:
ALLYLTRIISOPROPYLSILANE is utilized as a component in the preparation of silicon-containing polymers and materials, contributing to the development of advanced materials with specific properties.
Used in the Field of Organic Chemistry Research:
Due to its reactivity and structural features, ALLYLTRIISOPROPYLSILANE is a valuable tool in the field of organic chemistry research, enabling the exploration of new synthetic pathways and the development of innovative chemical processes.
Check Digit Verification of cas no
The CAS Registry Mumber 24400-84-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,4,4,0 and 0 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 24400-84:
(7*2)+(6*4)+(5*4)+(4*0)+(3*0)+(2*8)+(1*4)=78
78 % 10 = 8
So 24400-84-8 is a valid CAS Registry Number.
InChI:InChI=1/C12H26Si/c1-8-9-13(10(2)3,11(4)5)12(6)7/h8,10-12H,1,9H2,2-7H3
24400-84-8Relevant articles and documents
Synthesis and reactions of donor cyclopropanes: efficient routes to cis- and trans-tetrahydrofurans
Dunn, Jonathan,Dobbs, Adrian P.
supporting information, p. 7386 - 7414 (2015/08/24)
Abstract A detailed study on the synthesis and reactions of silylmethylcyclopropanes is reported. In their simplest form, these donor-only cyclopropanes undergo Lewis acid promoted reaction to give either cis- or trans-tetrahydrofurans, with the selectivity being reaction condition-dependant. The adducts themselves are demonstrated to be an important scaffold for structural diversification. The combination of a silyl-donor group in a donor-acceptor cyclopropane with novel acceptor groups is also discussed.
Rhodium(II)-catalyzed stereoselective synthesis of allylsilanes
Guptill, David M.,Cohen, Carolyn M.,Davies, Huw M. L.
supporting information, p. 6120 - 6123 (2014/01/17)
The rhodium-catalyzed decomposition of 2-(triisopropylsilyl)ethyl aryl- and vinyldiazoacetates results in the stereoselective formation of Z-allylsilanes. The transformation is considered to proceed by silyl-directed intramolecular C-H functionalization to form a β-lactone intermediate followed by a silyl-activated extrusion of carbon dioxide.
Zinc-catalyzed nucleophilic substitution reaction of chlorosilanes with organomagnesium reagents
Murakami, Kei,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 1415 - 1417 (2009/06/28)
Zinc-catalyzed nucleophilic substitution reactions of chlo-rosilanes with organomagnesium reagents afford various tetraorganosilanes under mild reaction conditions. The reactions can be performed on large scale and allow efficient preparation of functionalized tetraorganosilanes.
