Tetrahedron Letters p. 5375 - 5378 (1985)
Update date:2022-08-02
Topics:
Muchowski, Joseph M.
Naef, Reto
Maddox, Michael L.
The reaction of triisopropylsilylallyllithium with alkyl halides took place with considerably greater γ-selectivity than reported for trimethylsilyl allyllithium.Silica gel induced rearrangement of the epoxides 5 derived from the alkylation products 3 gave α-triisopropylsilyl aldehydes 6 by a process in which silyl group transposition occurred with predominant inversion at the migration terminus.
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