Tetrahedron Letters p. 5375 - 5378 (1985)
Update date:2022-08-02
Topics:
Muchowski, Joseph M.
Naef, Reto
Maddox, Michael L.
The reaction of triisopropylsilylallyllithium with alkyl halides took place with considerably greater γ-selectivity than reported for trimethylsilyl allyllithium.Silica gel induced rearrangement of the epoxides 5 derived from the alkylation products 3 gave α-triisopropylsilyl aldehydes 6 by a process in which silyl group transposition occurred with predominant inversion at the migration terminus.
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Doi:10.1002/cmdc.201200102
(2012)Doi:10.1016/S0040-4020(01)87616-X
(1986)Doi:10.1021/ja002376i
(2000)Doi:10.1021/acs.joc.7b01226
(2017)Doi:10.1002/adsc.200700151
(2007)Doi:10.1002/chem.201503787
(2015)