Tetrahedron Letters p. 5375 - 5378 (1985)
Update date:2022-08-02
Topics:
Muchowski, Joseph M.
Naef, Reto
Maddox, Michael L.
The reaction of triisopropylsilylallyllithium with alkyl halides took place with considerably greater γ-selectivity than reported for trimethylsilyl allyllithium.Silica gel induced rearrangement of the epoxides 5 derived from the alkylation products 3 gave α-triisopropylsilyl aldehydes 6 by a process in which silyl group transposition occurred with predominant inversion at the migration terminus.
View MoreShanghai Hanshare Industry Co.,Ltd.
Contact:86 21 20960688
Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
Contact:+44 (0)2036089360-31
Address:Chanceryhouse,Chancery Lan
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.
Contact:86-532-88250866
Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Contact:0086-22-2822 1962 / 2822 1963
Address:B-808, No. 1, North-South Street, Hexi District,
Doi:10.1002/cmdc.201200102
(2012)Doi:10.1016/S0040-4020(01)87616-X
(1986)Doi:10.1021/ja002376i
(2000)Doi:10.1021/acs.joc.7b01226
(2017)Doi:10.1002/adsc.200700151
(2007)Doi:10.1002/chem.201503787
(2015)
