451463-08-4

Upstream product

• 68681-00-5 3,4,6-tri-O-benzyl-1,2-O-<1-(R)-methoxyethylidene>-β-D-mannopyranose 
• 104639-36-3 3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 124684-91-9 2-O-acetyl-3,4,6-tri-O-benzyl-1-deoxy-α-D-mannopyranosyl fluoride 
• 146864-77-9 3,4,6-tri-O-benzyl-1,2-O-(exo-methoxyethylidene)-β-D-mannopyranose 
• 358351-59-4 2-O-allyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 

Downstream Products

• 358351-75-4 2-O-(2-iodo-1-(methyl-2,3,4-tri-O-benzyl-α-D-mannopyranosid-6-O-yl)-propyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 244282-24-4 cyclohexyl 3,4,6-tri-O-benzyl-β-D-mannopyranoside 
• 112330-11-7 (3,4,6-tri-O-benzyI-β-D-mannopyranosyl)-(1→6)-1,2,3,4-di-O-isoprpopylidene-α-D-galactopyranoside 
• 358351-73-2 2-O-(1-cyclohexyloxy-2-iodopropyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-74-3 2-O-(1-(1,2:3,4-di-O-isopropylidene-α-D-galactopyranos-6-O-yl)-2-iodopropyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-77-6 2-O-(2-iodo-1-(methyl-2,3,6-tri-O-benzyl-α-D-mannopyranosid-4-O-yl)-propyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-76-5 2-O-(2-iodo-1-(methyl-2-O-benzyl-4-6-O-benzylidene-α-D-mannopyranosid-3-O-yl)-propyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-68-5 2-O-(2-iodo-1-methoxypropyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 

Relevant academic research and scientific papers

Allyl protecting group mediated intramolecular aglycon delivery (IAD) of glycosyl fluorides

Stereospecific 1,2-cis-glycosylation of 2-O-allyl protected glucosyl and mannosyl fluorides can be achieved via a sequence of allyl isomerization, N-iodosuccinimide mediated tethering, and intramolecular aglycon delivery (IAD). Fluoride is advantageous as

Stereospecific synthesis of 1,2-cis glycosides by allyl-mediated intramolecular aglycon delivery. 2.The use of glycosyl fluorides.

[reaction: see text] Stereospecific 1,2-cis glycosylation of 2-O-allyl-protected glucosyl and mannosyl fluorides via a sequence of allyl isomerization, N-iodosuccinimide-mediated tethering, and intramolecular aglycon delivery (IAD) is reported. The use of