358351-73-2

Upstream product

• 358351-59-4 2-O-allyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 124684-91-9 2-O-acetyl-3,4,6-tri-O-benzyl-1-deoxy-α-D-mannopyranosyl fluoride 
• 68681-00-5 3,4,6-tri-O-benzyl-1,2-O-<1-(R)-methoxyethylidene>-β-D-mannopyranose 
• 108-93-0 cyclohexanol 
• 451463-08-4 (Z)-2-O-prop-1'-enyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 104639-36-3 3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 
• 358351-64-1 2-O-prop-1'-enyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl fluoride 

Downstream Products

• 244282-24-4 cyclohexyl 3,4,6-tri-O-benzyl-β-D-mannopyranoside 

Relevant academic research and scientific papers

Allyl protecting group mediated intramolecular aglycon delivery (IAD) of glycosyl fluorides

Stereospecific 1,2-cis-glycosylation of 2-O-allyl protected glucosyl and mannosyl fluorides can be achieved via a sequence of allyl isomerization, N-iodosuccinimide mediated tethering, and intramolecular aglycon delivery (IAD). Fluoride is advantageous as

Stereospecific synthesis of 1,2-cis glycosides by allyl-mediated intramolecular aglycon delivery. 2.The use of glycosyl fluorides.

[reaction: see text] Stereospecific 1,2-cis glycosylation of 2-O-allyl-protected glucosyl and mannosyl fluorides via a sequence of allyl isomerization, N-iodosuccinimide-mediated tethering, and intramolecular aglycon delivery (IAD) is reported. The use of