104750-45-0

Upstream product

• 53282-55-6 (trimethylsiloxymethylidene)cyclohexane 
• 104750-43-8 (1RS,2SR)-3-(t-butyldiphenylsiloxy)-2-methyl-1-<1-(phenylthio)cyclohexyl>propan-1-ol 
• 104750-38-1 (2RS,3SR)-2,6-dimethylphenyl 3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propionate 
• 104750-41-6 (1RS,2RS)-2-methyl-1-<1-(phenylthio)cyclohexyl>propane-1,3-diol 
• 104750-43-8 (1RS,2RS)-3-(t-butyldiphenylsiloxy)-2-methyl-1-<1-(phenylthio)cyclohexyl>propan-1-ol 
• 104750-47-2 (2RS,3SR)-methyl 3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propionate 
• 57768-35-1 1-(phenylthio)-1-cyclohexanecarboxaldehyde 
• 104750-47-2 (2R,3R)-3-Hydroxy-2-methyl-3-(1-phenylsulfanyl-cyclohexyl)-propionic acid methyl ester 
• 104750-44-9 (1'RS,2'RS)-1-<3'-(t-butyldiphenylsiloxy)-2'-methyl-1'-(phenylthio)propyl>cyclohexene 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 104750-44-9 (1'RS,2'SR)-1-<3'-(t-butyldiphenylsiloxy)-2'-methyl-1'-(phenylthio)propyl>cyclohexene 
• 2043-61-0 cyclohexanecarbaldehyde 
• 104750-41-6 (1R,2S)-2-Methyl-1-(1-phenylsulfanyl-cyclohexyl)-propane-1,3-diol 

Downstream Products

• 104750-46-1 <1RS,2'SR>-(E)-2-<3'-(t-butyldiphenylsiloxy)-2'-methylpropylidene>cyclohexanol 
• 104750-58-5 (1RS,2'SR)-(E)-<3'-(t-butyldiphenylsiloxy)-2'-methylpropylidene>cyclohexyl 3,5-dinitrobenzoate 
• 104750-46-1 (1RS,2'RS)-2-<3'-(t-butyldiphenylsiloxy)-2'-methylpropylidene>cyclohexanol 
• 133030-76-9 (1RS,2'RS)-(E)-2-(3'-hydroxy-2'-methylpropylidene)cyclohexanol 

Relevant academic research and scientific papers

Transformation of Cyclic α-Phenylthio Aldehydes by Stereoselective Aldol Reactions and Phenylthio Migration into Spirocyclic Lactones and Ethers, and E-Allylic Alcohols with 1,4-Related Chiral Centres

syn- and anti-Selective aldol reactions between enolates of propionate esters and three α-phenylthio cycloalkanecarbaldehydes give single diastereoisomers of phenylthio alcohols which rearrange in acid with 5-hydroxy or 5-CO2H participation to give spiroc

PHENYLTHIO(PhS) MIGRATION IN THE STEREOCONTROLLED SYNTHESIS OF ALLYLIC ALCOHOLS WITH 1,4 RELATED CHIRAL CENTRES.

Stereoselective aldol products are transformed by PhS migration into lactones, tetrahydrofurans, and, by subsequent Evans-Mislow rearrangement, into the title compounds with complete stereochemical control.