104750-58-5

Upstream product

• 53282-55-6 (trimethylsiloxymethylidene)cyclohexane 
• 104750-38-1 (2RS,3SR)-2,6-dimethylphenyl 3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propionate 
• 104750-43-8 (1RS,2RS)-3-(t-butyldiphenylsiloxy)-2-methyl-1-<1-(phenylthio)cyclohexyl>propan-1-ol 
• 104750-44-9 (1'RS,2'SR)-1-<3'-(t-butyldiphenylsiloxy)-2'-methyl-1'-(phenylthio)propyl>cyclohexene 
• 104750-45-0 (3-Benzenesulfinyl-3-cyclohex-1-enyl-2-methyl-propoxy)-tert-butyl-diphenyl-silane 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 104750-43-8 (1RS,2SR)-3-(t-butyldiphenylsiloxy)-2-methyl-1-<1-(phenylthio)cyclohexyl>propan-1-ol 
• 104750-47-2 (2R,3R)-3-Hydroxy-2-methyl-3-(1-phenylsulfanyl-cyclohexyl)-propionic acid methyl ester 
• 104750-41-6 (1RS,2RS)-2-methyl-1-<1-(phenylthio)cyclohexyl>propane-1,3-diol 
• 57768-35-1 1-(phenylthio)-1-cyclohexanecarboxaldehyde 
• 104750-44-9 (1'RS,2'RS)-1-<3'-(t-butyldiphenylsiloxy)-2'-methyl-1'-(phenylthio)propyl>cyclohexene 
• 99-33-2 3,5-dinitrobenoyl chloride 
• 104750-46-1 <1RS,2'SR>-(E)-2-<3'-(t-butyldiphenylsiloxy)-2'-methylpropylidene>cyclohexanol 

Relevant academic research and scientific papers

Transformation of Cyclic α-Phenylthio Aldehydes by Stereoselective Aldol Reactions and Phenylthio Migration into Spirocyclic Lactones and Ethers, and E-Allylic Alcohols with 1,4-Related Chiral Centres

syn- and anti-Selective aldol reactions between enolates of propionate esters and three α-phenylthio cycloalkanecarbaldehydes give single diastereoisomers of phenylthio alcohols which rearrange in acid with 5-hydroxy or 5-CO2H participation to give spiroc