104889-68-1Relevant academic research and scientific papers
Transfer hydrogenation of isoquinolinium salts catalyzed by a rhodium complex
Wu, Jiashou,Liao, Jian,Zhu, Jin,Deng, Jingen
, p. 2059 - 2062 (2006)
Regio- and chemoselective transfer hydrogenation of isoquinolinium salts catalyzed by [Cp*RhCl2]2 using HCOOH-Et3N (5:2) as a hydrogen source was realized. A variety of N-methyl- and N-benzyl-1,2,3,4-tetrahydroisoquinoline
One-Pot Olefin Isomerization/Aliphatic Enamine Ring-Closing Metathesis/Oxidation/1,3-Dipolar Cycloaddition for the Synthesis of Isoindolo[1,2-a]isoquinolines
Fujii, Yuki,Takehara, Tsunayoshi,Suzuki, Takeyuki,Fujioka, Hiromichi,Shuto, Satoshi,Arisawa, Mitsuhiro
, p. 4055 - 4062 (2016/01/25)
N-Alkyl-N-(2-vinylbenzyl)prop-2-en-1-amine derivatives undergo a one-pot olefin isomerization/aliphatic enamine ring-closing metathesis (RCM)/oxidation/1,3-dipolar cycloaddition sequence with the ruthenium complex, Ru(CO)HCl(PPh3)3, a second generation Hoveyda-Grubbs catalyst, and a 1,3-dipolarophile. Overall, in a single operation the reaction sequence converts simple benzylamine derivatives into isoindolo[1,2-a]isoquinolines with a π-conjugated four-ring system, through three unique ruthenium-catalyzed transformations.
STEREOCHIMIE DE LA CYCLOADDITION DES DIARYLNITRILIMINES SUR LES N-ALKYL ET LES DIALKYL-1,2 DIHYDRO-1,2 ISOQUINOLEINES
Kitane, Said,Tshiamala, Kabula,Laude, Bernard,Vebrel, Joeel,Cerutti, Ernest
, p. 3737 - 3751 (2007/10/02)
The PMR spectroscopic properties (60 MHz) of cycloadducts of diarylnitrilimins towards 1,2-dihydroisoquinolines mono alkylated at the N-atom or dialkylated at the C1-carbon and N-atoms have been studied.Date allow us to determine the stereochemistry of th
