105-84-0Relevant articles and documents
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Shashoua,Eareckson
, p. 343,345 (1959)
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Reaction of 1,2-dibromoethane with primary amines: Formation of N,N′-disubstituted ethylenediamines RNH-CH2CH2-NHR and homologous polyamines RNH-[CH2CH2NR]n-H
Denk, Michael K.,Krause, Mike J.,Niyogi, Debyani F.,Gill, Nachhattarpal K.
, p. 7565 - 7570 (2007/10/03)
The reaction of primary amines RNH2 (R: Me, Et, iPr, tBu and Ph) with 1,2-dibromoethane gave N,N′-disubstituted ethylenediamines R-NH-CH2CH2-NH-R (1) in yields ranging from 10% (1a; R=Me) to 70% (1d, R=tBu; 1e, R=Ph). Pipe
Synthesis and Protonation Behaviour of the Macrocyclic Ligand 1,4,7,13-Tetramethyl-1,4,7,10,13,16-hexaazacyclooctadecane and of its Bicyclic Derivative 4,7,10,17,23-Pentamethyl-1,4,7,10,13,17,23-heptaazabicyclopentacosane. A Potentiometric and 1H and 13C NMR Study
Bencini, Andrea,Bianchi, Antonio,Garcia-Espana, Enrique,Fusi, Vieri,Micheloni, Mauro,et al.
, p. 1059 - 1065 (2007/10/02)
The synthesis and characterization of the new macrocyclic ligand 1,4,7,13-tetramethyl-1,4,7,10,13,16-hexaazabicyclooctadecane (L) and of its bicyclic derivative 4,7,10,17,23-pentamethyl-1,4,7,10,13,17,23-heptaazabicyclopentacosane (L1) is reported.The basicity behaviour of both polyamines has been studied by potentiometry in 0,15 mol dm-3 NaClO4 solution at 298.15 K and the relevant protonation constants have been determined. 1H and 13C NMR spectroscopy of L and L1, at various pH values, allows the main features of the protonation patterns to be determined.