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ORGANOMETALLOIDAL DERIVATIVES OF THE TRANSITION METALS XI. SYNTHESIS AND CRYSTAL STRUCTURES OF Ph3GeSiMe3 AND Ph3GeSiMe2Fe(CO)2(η5-C5H5)
Parkanyi, Laszlo,Hernandez, Carlos,Pannell, Keith H.
, p. 145 - 152 (1986)
Ph3GeSiMe3 and Ph3GeSiMe2Fe(CO)2(η5-C5H5) have been synthesized and their crystal structures determined.The Ge-Si bond in iron (2.405(2) angstroem) is longer by 0.021 angstroem than in the simple germylsilane (2.384(1) angstroem).The significan
