105104-15-2

Basic information

• Product Name: 2-(benzyloxy)-4-methoxy-3-methylphenyl 2,4-pentadienyl ether
• Synonyms: 2-(benzyloxy)-4-methoxy-3-methylphenyl 2,4-pentadienyl ether
• CAS NO: 105104-15-2
• Molecular Weight: 310.393
• Mol File: 105104-15-2.mol

Chemical Properties

• CAS DataBase Reference: 2-(benzyloxy)-4-methoxy-3-methylphenyl 2,4-pentadienyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzyloxy)-4-methoxy-3-methylphenyl 2,4-pentadienyl ether(105104-15-2)
• EPA Substance Registry System: 2-(benzyloxy)-4-methoxy-3-methylphenyl 2,4-pentadienyl ether(105104-15-2)

Safety Data

• Hazardous Substances Data: 105104-15-2(Hazardous Substances Data)

Upstream product

• 40596-30-3 penta-2,4-dienyl chloride 
• 105103-95-5 2-(benzyloxy)-4-methoxy-3-methylphenol 
• 6971-52-4 3-methoxy-2-methylphenol 
• 105104-09-4 2-benzyloxy-4-methoxy-3-methylbenzaldehyde 
• 54700-36-6 2-hydroxy-4-methoxy-3-methylbenzaldehyde 
• 922-65-6 divinylcarbinol 
• 100-39-0 benzyl bromide 

Downstream Products

• 105104-26-5 2-(benzyloxy)-4-methoxy-3-methyl-5-(2,4-pentadienyl)phenol 

Relevant articles and documents

Lewis Acid Mediated Claisen-Type Rearrangement of Aryl Dienyl Ethers

Rearrangement of aryl pentadienyl ethers in the presence of BF3*OEt2 affords pentadienyl phenols in good yields without formation of the corresponding rearranged products.The mechanism of this rearrangement was studied by deuterium labeling and cross-coupling reactions.The scope and limitations of the rearrangement are discussed.