105103-95-5Relevant articles and documents
Syntheses of the antibiotic alkaloids renierone, mimocin, renierol, renierol acetate, renierol propionate, and 7-methoxy-1,6-dimethylisoquinoline-5, 8-dione
Kuwabara, Nagako,Hayashi, Hiroyuki,Hiramatsu, Noriko,Choshi, Tominari,Kumemura, Teppei,Nobuhiro, Junko,Hibino, Satoshi
, p. 2943 - 2952 (2007/10/03)
The total synthesis of renierone, mimocin, renierol, renierol acetate, renierol propionate, and 7-methoxy-1,6-dimethylisoquinoline-5,8-dione was successfully achieved by the regioselective oxidation of 5-oxygenated isoquinoline. The synthetic method of the 5-oxygenated isoquinoline is based on the thermal electrocyclic reaction of 1-azahexatriene system involving the benzene 1,2-bond.
Lewis Acid Mediated Claisen-Type Rearrangement of Aryl Dienyl Ethers
Maruyama, Kazuhiro,Nagai, Naoshi,Naruta, Yoshinori
, p. 5083 - 5092 (2007/10/02)
Rearrangement of aryl pentadienyl ethers in the presence of BF3*OEt2 affords pentadienyl phenols in good yields without formation of the corresponding rearranged products.The mechanism of this rearrangement was studied by deuterium labeling and cross-coupling reactions.The scope and limitations of the rearrangement are discussed.