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105122-15-4

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105122-15-4 Usage

General Description

(5S)-(5-tert-butyldimethylsiloxymethyl)furan-2(5H)-one is a chemical compound with the molecular formula C12H22O3Si. It is a furan derivative with a tert-butyldimethylsiloxy group attached to the 5th carbon atom. (5S)-(5-TERT-BUTYLDIMETHYLSILOXYMETHYL)FURAN-2(5H)-ONE has potential applications in pharmaceuticals, agrochemicals, and materials science due to its unique structure and properties. It may be used as a building block in the synthesis of various organic compounds and could also have potential biological activities. Further research and studies are needed to fully understand the potential uses and properties of this chemical.

Check Digit Verification of cas no

The CAS Registry Mumber 105122-15-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,5,1,2 and 2 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 105122-15:
(8*1)+(7*0)+(6*5)+(5*1)+(4*2)+(3*2)+(2*1)+(1*5)=64
64 % 10 = 4
So 105122-15-4 is a valid CAS Registry Number.

105122-15-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 5-O-(tert-butyldimethylsilyl)-2,3-dideoxy-L-glyceropentonic acid γ-lactone

1.2 Other means of identification

Product number -
Other names .(S)-5-tert-butyldimethylsilyloxy-2-penten-4-olide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:105122-15-4 SDS

105122-15-4Relevant articles and documents

Catalytic ferrier rearrangement of unsaturated nucleosides

Linker, Torsten,Sommermann, Thomas,Gimisis, Thanasis,Chatgilialoglu, Chryssostomos

, p. 9637 - 9638 (1998)

The attempted intermolecular addition of malonyl radicals to 1',2'- unsaturated nucleosides has led to the unexpected formation of furanones. Thus, only catalytic amounts of ceric(IV) ammonium nitrate (CAN), induce a Ferrier rearrangement. The unsaturated lactone was isolated in good yield and can serve as a precursor for the synthesis of optically active products.

Synthesis and antiviral activity of the cyclopropano homolog of 2,3- didehydro-2,3-dideoxythymidine

Sard

, p. 2321 - 2328 (1994)

2,3-Didehydro-2,3-dideoxythymidine is among the nucleoside analogs which have been shown to be clinically useful as anti-HIV agents. Its 2,3- cyclopropano analog has now been synthesized and evaluated. However, the title compound is inactive against HIV.

A facile entry to bicyclic systems from L-glutamic acid

Frieman, Bryan A.,Bock, Charles W.,Bhat, Krishna L.

, p. 2099 - 2108 (2001)

An efficient synthesis of bicyclic heterocycles has been realized from L-glutamic acid. The key step is the construction of the pyrrole ring in a single step, using tosylmethyl isocyanide (TosMIC) methodology. Structures of reaction intermediates and final products were investigated using density functional theory calculations.

The use of d-mannitol-derived C2-symmetric trienes in tandem metathesis reactions towards valuable lactones

Riache, Nassima,Blond, Alain,Nay, Bastien

, p. 10853 - 10859 (2008)

Chiral lactones were synthesized from d-mannitol. C2-symmetric triene precursors were constructed with a central relay-olefin allowing the key domino ring-closing metathesis to be achieved. It led to the symmetrical cleavage of the substrate and to the formation of 2 mol of the desired 5- or 6-membered lactone. Attempts to form 7-membered lactones thus far only led to 14-membered macrodiolides instead.

Process for Preparing Beraprost Intermediate

-

Paragraph 0160; 0161, (2018/01/05)

The present invention relates to a method of producing an intermediate necessary for the production of 314d isomer of beraprost in a high yield and in mild reaction conditions. According to the present invention, the method can produce a compound of chemical formula 3 in a high yield, which is a major intermediate necessary for the production of 314d isomer of beraprost, in mild reaction conditions.COPYRIGHT KIPO 2017

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