105230-46-4Relevant academic research and scientific papers
A general animation method based on the addition of polyfunctional arylmagnesium reagents to functionalized arylazo tosylates
Sapountzis, Ioannis,Knochel, Paul
, p. 897 - 900 (2004)
A one-pot reaction sequence consisting of a Grignard reaction, allylation, and reduction provides new functionalized diarylamines in good yields (see scheme, Ts = toluene-4-sulfonyl, NMP = N-methylpyrrolidine, TFA = trifluoroacetic acid). In the first ste
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates
Del Amo, Vicente,Dubbaka, Srinivas Ready,Krasovskiy, Arkady,Knochel, Paul
, p. 7838 - 7842 (2007/10/03)
(Chemical Equation Presented). A tolerant reaction: Functionalized tertiary amines have been prepared by the oxidative coupling of amidocuprates with chloranil used as the oxidant (see Scheme). A high tolerance of functional groups and insensitivity to steric hindrance characterize this general amination reaction.
