105361-41-9Relevant academic research and scientific papers
A NOVEL RETRO-ENE REACTION THE FRAGMENTATION OF N-BENZYL-2-BENZOYL-2-METHYLPROPANIMINE
Armesto, Diego,Ramos, Ana,Perez-Ossorio, Rafael
, p. 5195 - 5198 (1982)
N-benzyl-2-benzoyl-2-methylpropanimine treated with nucleophiles undergoes a fragmentation reaction that can be envisaged as a retro-ene reaction via the formation of an intermediate hemiketal.
Synthesis and Reactions of Novel Substituted 3-Hydroxy-5-iminoalkanoic Esters
Alcaide, Benito,Alajarin, Ramon,Plumet, Joaquin,Rodriguez-Lopez, Julian
, p. 440 - 444 (2007/10/02)
The title compounds 4 were prepared from β-iminoketones 2 by reaction with simple α-lithiated esters 3 through a thermally controlled process.Some reactions of the title compounds 4 are also reported, in spite of their facile thermolysis.
Photochemical Reactivity of Aldimines from 2,2-Dimethyl-3-oxo-3-phenylpropanal
Armesto, Diego,Ramos, Ana,Perez-Ossorio, Rafael,Horspool, William M.
, p. 91 - 94 (2007/10/02)
The syntheses of some thermally labile aldimines of 2,2-dimethyl-3-oxo-3-phenylpropanal are described.The aldimines (7a-c) are photochemically reactive and undergo fission mainly into isopropyl phenyl ketone.Several other minor products are also formed.On
