105590-24-7Relevant academic research and scientific papers
Synthesis and reactions of benzopentathiepin having hydroxyl group
Sato, Ryu,Fujio, Toshiyuki,Nakajo, Shiduko,Ogawa, Satoshi,Alam, Ashraful
, p. 3013 - 3016 (2007)
The synthesis of benzopentathiepin having a hydroxyl group at the neighboring position of polysulfur ring was performed by demethylation of 6-ethyl-9-methoxybenzopentathiepin with hydrogenbromide. Benzotrithiole having hydroxyl group was not isolated at a
Nitrocyclohexadienones : a new class of nitrating agents
Lemaire, Marc,Guy, Alain,Roussel, Jacques,Guette, Jean-paul
, p. 835 - 844 (2007/10/02)
Various nitrocyclohexadienones are proposed as new nitrating agents. These compounds are easy to prepare from corresponding phenols, easy to handle and stable. Nitrocyclohexadienones act as nitronium carriers using rearomatization as the driving force and permit nitration of highly activated substrates under mild conditions and with good yields.
The Nitration of some 4-Alkylphenols; Acid-Catalysed Rearrangements of Some Polysubstituted 4-Alkyl-4-hydroxycyclohexa-2,5-dienones
Gray, Michael J.,Hartshorn, Michael P.,Vaughan, John
, p. 59 - 68 (2007/10/02)
The nitrations of 4-methyl (6a) and 4-ethyl (9a) tetrabromo phenols, and 4-methyl (6b) and 4-ethyl (9b) 2,3,5-tribromo-6-nitrophenols are described.The acid-catalysed rearrangements of 4-alkyl-4-hydroxycyclohexa-2,5-dienones (7a,b) and (8a,b) in concentrated sulfuric acid are described, and the effects of the nature of the C4-alkyl group and C6-substituent (Br or NO2) on the observed reactions are discussed.
