1056016-21-7

Basic information

• Product Name: 3-((tert-butyldimethylsilyl)oxy)propyl benzoate
• Synonyms: 3-((tert-butyldimethylsilyl)oxy)propyl benzoate
• CAS NO: 1056016-21-7
• Molecular Weight: 294.466
• Mol File: 1056016-21-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-((tert-butyldimethylsilyl)oxy)propyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-((tert-butyldimethylsilyl)oxy)propyl benzoate(1056016-21-7)
• EPA Substance Registry System: 3-((tert-butyldimethylsilyl)oxy)propyl benzoate(1056016-21-7)

Safety Data

• Hazardous Substances Data: 1056016-21-7(Hazardous Substances Data)

Upstream product

• 203738-77-6 3-tert-butyldimethylsilyloxy-1-propyl benzyl ether 
• 10364-94-0 1-benzoylimidazole 
• 73842-99-6 3-tert-butyldimethylsilyloxy-1-propanol 

Downstream Products

• 6946-99-2 3-hydroxypropyl benzoate 

Relevant articles and documents

Visible-Light Photocatalysis Employing Dye-Sensitized Semiconductor: Selective Aerobic Oxidation of Benzyl Ethers

The aerobic oxidation is an attractive approach toward environmentally benign synthesis of fine chemicals. In addition, dye-sensitized semiconductors are underdeveloped photocatalysts for selective organic synthesis. With the aid of catalytic eosin Y-sensitized titanium dioxide, we have developed efficient aerobic photooxidation of benzyl ethers to benzoates, featuring low cost, high atom economy, broad substrate scope, and user-friendly setup. Furthermore, preliminary mechanistic studies established that the reaction pathway likely entails a photoinduced, radical-based two-step process via an isolable peroxide intermediate.