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203738-77-6

Silane, (1,1-dimethylethyl)dimethyl[3-(phenylmethoxy)propoxy]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 203738-77-6 Structure

  • Basic information

    1. Product Name: Silane, (1,1-dimethylethyl)dimethyl[3-(phenylmethoxy)propoxy]-
    2. Synonyms:
    3. CAS NO:203738-77-6
    4. Molecular Formula: C16H28O2Si
    5. Molecular Weight: 280.483
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 203738-77-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Silane, (1,1-dimethylethyl)dimethyl[3-(phenylmethoxy)propoxy]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Silane, (1,1-dimethylethyl)dimethyl[3-(phenylmethoxy)propoxy]-(203738-77-6)
    11. EPA Substance Registry System: Silane, (1,1-dimethylethyl)dimethyl[3-(phenylmethoxy)propoxy]-(203738-77-6)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 203738-77-6(Hazardous Substances Data)

203738-77-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 203738-77-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,0,3,7,3 and 8 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 203738-77:
(8*2)+(7*0)+(6*3)+(5*7)+(4*3)+(3*8)+(2*7)+(1*7)=126
126 % 10 = 6
So 203738-77-6 is a valid CAS Registry Number.

203738-77-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-tert-butyldimethylsilyloxy-1-propyl benzyl ether

1.2 Other means of identification

Product number -
Other names 1-benzyloxy-3-(tert-butyldimethylsilyl)oxypropane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:203738-77-6 SDS

203738-77-6Relevant articles and documents

Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes

Jones, Caleb A. H.,Schley, Nathan D.

supporting information, p. 1744 - 1748 (2019/02/20)

Catalysts capable of heterolytic silane activation have been successfully applied to the conversion of alkyl ethers to silyl ethers via C-O bond cleavage. The previously-reported cationic pincer-supported iridium complex for this transformation suffers fr

Solvent-modulated Pd/C-catalyzed deprotection of silyl ethers and chemoselective hydrogenation

Ikawa, Takashi,Hattori, Kazuyuki,Sajiki, Hironao,Hirota, Kosaku

, p. 6901 - 6911 (2007/10/03)

Recently we have reported undesirable and frequent deprotection of the TBDMS protective group of a variety of hydroxyl functions occurred under neutral and mild hydrogenation conditions using 10% Pd/C in MeOH. The deprotection of silyl ethers is susceptible to significant solvent effect. TBDMS and TES protecting groups were selectively cleaved in the presence of acid-sensitive functional groups such as TIPS ether, TBDPS ether and dimethyl acetal under hydrogenation condition using 10% Pd/C in MeOH. In contrast, chemoselective hydrogenation of reducible functional groups such as acetylene, olefin and benzyl ether, proceeds in the presence of TBDMS or TES ethers in AcOEt or MeCN.

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