105643-15-0

Basic information

• Product Name: 2-Propen-1-ol, 3-(4-chlorophenyl)-, acetate
• CAS NO: 105643-15-0
• Molecular Formula: C11H11ClO2
• Molecular Weight: 210.66
• Mol File: 105643-15-0.mol

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-ol, 3-(4-chlorophenyl)-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-ol, 3-(4-chlorophenyl)-, acetate(105643-15-0)
• EPA Substance Registry System: 2-Propen-1-ol, 3-(4-chlorophenyl)-, acetate(105643-15-0)

Safety Data

• Hazardous Substances Data: 105643-15-0(Hazardous Substances Data)

Upstream product

• 637-87-6 1-Chloro-4-iodobenzene 
• 591-87-7 Allyl acetate 
• 24583-70-8 3-(4-chlorophenyl)-2-propene-1-ol 
• 108-24-7 acetic anhydride 
• 58824-54-7 p-chlorophenylvinylcarbinol 

Downstream Products

• 1607805-20-8 C₁₀H₈BrClF₂ 
• 1607804-96-5 C₁₃H₁₃ClF₂ 
• 1514677-27-0 (R)-5-((R)-1-(4-chlorophenyl)allyl)-2-(4-methoxyphenyl)-5-methyloxazol-4(5H)-one 
• 101282-51-3 C₁₆H₁₅ClO 
• 1147357-09-2 C₁₆H₁₅Cl 
• 20442-76-6 1-(4-chloro-phenyl)-3-phenyl-propene 

Relevant articles and documents

Enantioselective synthesis of 3-substituted dihydrobenzofurans through iridium-catalyzed intramolecular hydroarylation

Intramolecular hydroarylationviaC-H activation is one of the most powerful methods to synthesize carbo- and heterocyclic compounds, whereas we still have room for developing a highly enantioselective variant of the reaction. Here we describe Ir-catalyzed enantioselective intramolecular hydroarylation ofm-allyloxyphenyl ketones. The enantioselective cyclization was efficiently catalyzed by a cationic iridium complex coordinated with a conventional chiral bisphosphine ligand to give benzofurans in high yields with high enantioselectivity. A carbonyl group of ketones functioned as an effective directing group for the C-H activation. In terms of synthetic utility, we also achieved one-pot synthesis of chiral 3-substituted dihydrobenzofurans from readily available allylic carbonates andm-hydroxyacetophenonesviasequential Pd-catalyzed allylic substitution and Ir-catalyzed intramolecular hydroarylation.

Oxygenation of Simple Olefins through Selective Allylic C?C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes

A novel metal-free allylic C?C σ-bond cleavage of simple olefins to give valuable cinnamyl aldehydes is reported. 1,2-Aryl or alkyl migration through allylic C?C bond cleavage occurs in this transformation, which is assisted by an alkyl azide reagent. This method enables O-atom incorporation into simple unfunctionalized olefins to construct cinnamyl aldehydes. The reaction features simple hydrocarbon substrates, metal-free conditions, and high regio- and stereoselectivity.

Stereoselective and Site-Specific Allylic Alkylation of Amino Acids and Small Peptides via a Pd/Cu Dual Catalysis

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Sterically controlled alkylation of arenes through iridium-catalyzed C-H borylation

Complementary chemistry: A one-pot method for the site-selective alkylation of arenes controlled by steric effects is reported. The process occurs through Ir-catalyzed C-H borylation, followed by Pd- or Ni-catalyzed coupling with alkyl electrophiles. This selectivity complements that of the typical Friedel-Crafts alkylation; meta-selective alkylation of a broad range of arenes with various electronic properties and functional groups occurs in good yield with high site selectivity. Copyright