10581-28-9Relevant academic research and scientific papers
Synthesis of 6-tert-octyl and 6,8-ditert-butyl coumarins, two coumarins of biological interest
Arroyo, P.,Darouch, M.,Lisboa, E.,Miranda, A.,Zárraga, M.
, p. 5220 - 5222 (2021/07/12)
In this study, the synthesis of new coumarins with aliphatic chains is discussed. The incorporation of the 6-tert-octyl and 6,8-ditert-butyl chains into a coumarin structure from alkylphenols, allows obtaining hydrophobic coumarins with good yields. These coumarins can be potential modulators of TRPV1 receptors. Synthesis and spectroscopic data of these new coumarins are analyzed.
The Rich Tautomeric Behavior of Campestarenes
Chen, Zhengyu,Guieu, Samuel,White, Nicholas G.,Lelj, Francesco,MacLachlan, Mark J.
supporting information, p. 17657 - 17672 (2016/11/29)
Campestarenes are a new family of Schiff-base macrocycles that form selectively in a one-step synthesis. These macrocycles with five-fold symmetry show solvent-dependent tautomerization and dimerization or aggregation. In this paper, we have prepared new
Campestarenes: Novel shape-persistent Schiff base macrocycles with 5-fold symmetry
Guieu, Samuel,Crane, Angela K.,MacLachlan, Mark J.
supporting information; experimental part, p. 1169 - 1171 (2011/03/20)
A simple 1-step procedure yields a family of easily modifiable, stable, conjugated Schiff base macrocycles with 5-fold symmetry mediated by 3-center hydrogen bonding.
The separation and synthesis of lipidic 1,2- and 1,3-diols from natural phenolic lipids for the complexation and recovery of boron
Tyman, John H.P.,Mehet, Satinderjit K.
, p. 177 - 199 (2007/10/03)
A study has been made of the semi-synthesis of 1,3-diols (anacardic alcohols) from natural phenolic lipid resources from Anacardium occidentale and Anacardium giganteum which have given C15 and C11 derivatives, respectively. An isomeric 1,3-diol (isoanacardic alcohol) has been obtained from cardanol separated from technical cashew nut-shell liquid. Homologous1,3-diols have been synthesised from a range of synthetic 2-alkyl-, 3-alkyl- and 4-alkylphenols and from 6-alkylsalicylic acids. The natural 1,2-diol, urushiol, from Rhus vernicifera has been purified. All these lipidic compounds have been studied for their complexation and the potential recovery of boron as boric acid.
Nickel complex catalyzed reduction of imines
Vetter,Berkessel
, p. 419 - 422 (2007/10/02)
The 1:1 complexes formed in situ from nickel(II) acetate and the thiosemicarbazones of ortho-hydroxy aromatic aldehydes catalyze the hydrosilylation of imines. A variety of imines were reduced in good to excellent yields employing two equivalents of a silane such as triethylsilane and 5 mol% of the catalysts.
