105882-02-8

Basic information

• Product Name: Benzenesulfonamide, N-2-hexenyl-4-methyl-
• CAS NO: 105882-02-8
• Molecular Formula: C13H19NO2S
• Molecular Weight: 253.365
• Mol File: 105882-02-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-2-hexenyl-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-2-hexenyl-4-methyl-(105882-02-8)
• EPA Substance Registry System: Benzenesulfonamide, N-2-hexenyl-4-methyl-(105882-02-8)

Safety Data

• Hazardous Substances Data: 105882-02-8(Hazardous Substances Data)

Upstream product

• 127-65-1 chloroamine-T 
• 90036-67-2 <(1-propyl-2-propenyl)seleno>benzene 
• 928-95-0 (E)-2-Hexen-1-ol 
• 27829-72-7 ethyl (E)-hex-2-enoate 
• 1026405-21-9 C₁₈H₂₇NO₄S 
• 107574-36-7 (2E)-hex-2-en-1-yl methyl carbonate 
• 18522-92-4 sodium p-toluenesulfonamide 
• 4050-45-7 trans-2-hexene 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 7688-21-3 cis-2-hexene 
• 592-41-6 1-hexene 

Downstream Products

• 1186219-49-7 (E)-N-(hex-2-enyl)-4-methyl-N-(3-methylbuta-1,2-dienyl)benzenesulfonamide 

Relevant articles and documents

A new selena-aza-payne-type rearrangement of aziridinylmethyl tosylates mediated by tetraselenotungstate

Tetraselenotungstate 1 reacts with simple (N-tosylaziridinyl)-methyl tosylate derivatives to give allylamine derivatives as the only products by an unprecedented selena-aza-Payne-type rearrangement. When the methodology is extended to disubstituted (N-tos

Rh(III)-Catalyzed C-H Activation-Initiated Directed Cyclopropanation of Allylic Alcohols

We have developed a Rh(III)-catalyzed diastereoselective [2+1] annulation onto allylic alcohols initiated by alkenyl C-H activation of N-enoxyphthalimides to furnish substituted cyclopropyl-ketones. Notably, the traceless oxyphthalimide handle serves three functions: Directing C-H activation, oxidation of Rh(III), and, collectively with the allylic alcohol, in directing cyclopropanation to control diastereoselectivity. Allylic alcohols are shown to be highly reactive olefin coupling partners leading to a directed diastereoselective cyclopropanation reaction, providing products not accessible by other routes.

Rhodium/Yanphos-Catalyzed Asymmetric Interrupted Intramolecular Hydroaminomethylation of trans-1,2-Disubstituted Alkenes

The first interrupted asymmetric hydroaminomethylation reaction was developed. The challenging trans-1,2-disubstituted olefins were employed as substrates, and a series of valuable chiral pyrrolidinones and pyrrolidines were obtained in high yields with high regioselectivities and excellent enantioselectivities. Several synthetic transformations were conducted, demonstrating the high synthetic utility of our method. A creative route for the synthesis of vernakalant and Enablex was also developed.