106124-30-5Relevant academic research and scientific papers
Heterocyclic Rearrangements. Synthesis of 1,2,4-Oxadiazolopyrimidinium Systems and Their Ring Opening into Pyrimidine N-Oxides
Buscemi, Silvestre,Macaluso, Gabriella,Frenna, Vincenzo,Vivona, Nicolo
, p. 1175 - 1177 (2007/10/02)
The reaction of 3-amino-5-phenyl-(methyl)-1,2,4-oxadiazole with acetylacetone or benzoylacetone in the presence of perchloric acid has been studied.Synthesis of 1,2,4-oxadiazolopyrimidinium perchlorates and their ring opening reaction into aminopyrimidine N-oxides is reported.
Heterocyclic Rearrangements: Rearrangement of N-(1,2,4-Oxadiazol-3-yl)-β-enamino Ketones into Pyrimidine N-Oxides
Vivona, Nicolo,Buscemi, Silvestre,Frenna, Vincenzo,Ruccia, Michele
, p. 17 - 20 (2007/10/02)
The behaviour of N-(5-R-1,2,4-oxadiazol-3-yl)-β-enamino ketones towards rearrangement has been investigated.In the presence of anionic reagents in ethanol solution, they rearrange to pyrimidine N-oxides.The synthesis and hydrolytic ring opening of a oxadiazolopyrimidinium system is also reported.
