106137-98-8

Basic information

• Product Name: Silane, (1,3-diphenyl-2-propenyl)trimethyl-, (E)-
• CAS NO: 106137-98-8
• Molecular Formula: C18H22Si
• Molecular Weight: 266.458
• Mol File: 106137-98-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, (1,3-diphenyl-2-propenyl)trimethyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,3-diphenyl-2-propenyl)trimethyl-, (E)-(106137-98-8)
• EPA Substance Registry System: Silane, (1,3-diphenyl-2-propenyl)trimethyl-, (E)-(106137-98-8)

Safety Data

• Hazardous Substances Data: 106137-98-8(Hazardous Substances Data)

Upstream product

• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 57482-85-6 <α-(trimethylsilyl)benzyl>magnesium bromide 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 
• 75-77-4 chloro-trimethyl-silane 
• 223438-91-3 1,3-diphenyl-2-propenyl pivalate 
• 116118-03-7 (E)-(3-methoxyprop-1-ene-1,3-diyl)dibenzene 

Downstream Products

• 16704-20-4 (E)-(prop-1-ene-1,3-diyl-3-deuterio)dibenzene 
• 85405-58-9 (Z)-1,3-diphenylpropene-3-d 
• 86234-22-2 1,3-diphenyl-1-(trimethylsilyl)propane 
• 60208-56-2 (R)-(+)-2-d₁-phenylethanol 
• 82545-36-6 (E)-(3R,4R)-2,2-Dimethyl-4,6-diphenyl-hex-5-en-3-ol 
• 82545-40-2 (E)-(3S,4R)-2,2-Dimethyl-4,6-diphenyl-hex-5-en-3-ol 
• 82545-44-6 (E)-(3S,4S)-2,2-Dimethyl-4,6-diphenyl-hex-5-en-3-ol 

Relevant articles and documents

Oxoammonium-Mediated Allylsilane–Ether Coupling Reaction

A new C(sp3)?H functionalization reaction consisting of the oxidative α-allylation of allyl- and benzyl- methyl ethers has been developed. The C?C coupling could be carried out under mild conditions thanks to the use of cheap and green oxoammonium salts. The scope of the reaction was studied over 27 examples, considering the nature of the substituents on the two coupling partners.

Nickel-Mediated Enantiospecific Silylation via Benzylic C-OMe Bond Cleavage

Benzylic stereocenters are found in bioactive and drug molecules, as enantiopure benzylic alcohols have been used to build such a stereogenic center, but are limited to the construction of a C-C bond. Silylation of alkyl alcohols has the potential to build bioactive molecules and building blocks; however, the development of such a process is challenging and unknown. Herein, we describe an unprecedented AgF-assisted nickel catalysis in the enantiospecific silylation of benzylic ethers.

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 3. Preparation of Optically Active Allylsilanes by Palladium-Catalyzed Asymmetric Grignard Cross-Coupling

Asymmetric cross-coupling of the - or -Grignard reagent with alkenyl bromides in the presence of a chiral ferrocenylphosphine-palladium complex, dichloroethylamine>palladium(II) (PdCl2), as a catalyst, gave optically active allylsilanes which contain an asymmetric carbon atom directly bonded to the silicon atom, e.g., (R)-3-phenyl-3-(trimethylsilyl)propene (3a) (95percent ee), (R,E)-1-phenyl-1-(trimethylsilyl)-2-butene (3b) (85percent ee), (R,Z)-3b (24percent ee), (R,E)-1,3-diphenyl-3- (trimethylsilyl)propene (3c) (95percent ee), (S,E)-1-phenyl-3-(trimethylsilyl)-1-butene (14c) (71percent ee), (S,Z)-14c (59percent ee), (S,E)-1-phenyl-3-(triethylsilyl)-1-butene (16c) (93percent ee), (S,E)-3-(triethylsilyl)-2-pentene (16b) (85percent ee), (S,E,E)-2-(dimethylphenylsilyl)-3,5-heptadiene (15d) (45percent ee), and 1-cyclopentene (21) (37percent ee).The configuration and enantiomeric purity of the allylsilanes were determined with the aid of stereoselective oxidative cleavage of the carbon-silicon bond in optically active alkylsilanes.