85405-58-9Relevant academic research and scientific papers
Preparation of meso-1,3-diphenylallyllithium·(-)-sparteine - Its crystal structure and reactions
Marr, Felix,Froehlich, Roland,Hoppe, Dieter
, p. 2587 - 2592 (2002)
The X-ray crystal structure of 1,3-diphenylallyllithium, complexed with enantiomerically pure (-)-sparteine, was determined. The crystallized complex is stereohomogeneous. Its subsequent electrophilic substitution reactions proceed with low enantioselecti
Direct Reduction of Allylic Alcohols Using Isopropanol as Reductant
Sai, Masahiro
, p. 3482 - 3487 (2018/09/14)
The lithium cation-catalyzed direct reduction of allylic alcohols to alkenes using isopropanol as a hydride donor was developed. The hydride transfer of the in situ-generated lithium isopropoxide to an allylic cation is the key process in this transformation. The reaction generates only water and acetone as byproducts, which highlights the synthetic utility of this method. (Figure presented.).
ANTI STEREOCHEMISTRY IN PROTODESILYLATION OF AN OPTICALLY ACTIVE ALLYLSILANE WITH TRRIFLUOROACETIC ACID-D
Hayashi, Tamio,Ito, Hiroshi,Kumada, Makoto
, p. 4605 - 4606 (2007/10/02)
SE' reaction of (R)-(E)-1,3-diphenyl-3-trimethylsilylpropene with trifluoroacetic acid-d proceeded with anti stereochemistry to give (R)-(E)-1,3-diphenylpropene-3-d.
