106368-90-5Relevant academic research and scientific papers
Reaction of Olefins with Anodically Generated Radical Cations of Trialkyl Phosphites and Dialkyl Trimethylsilyl Phosphites
Romakhin,Kosachev,Nikitin
, p. 1901 - 1908 (2007/10/03)
Electrochemical oxidation of trialkyl phosphites and dialkyl trimethylsilyl phosphites in the presence of olefins yields mixtures of isomeric dialkyl alkenyl(cycloalkenyl)phosphonates with predominating [alken(cycloalken)-2-yl]phosphonates. A scheme of the process was proposed, which involves attack of the alkene double bond by anodically generated radical cations of phosphites, followed by a second electron transfer, deprotonation, and elimination of cationic species: alkyl cation in the case of trialkyl phosphites and trimethylsilyl cation in the case trimethylsilyl phosphites.
The Stereochemistry of Organometallic Compounds. XXXVIII. Regio- and Stereo-control in the Rhodium-Catalysed Hydroformylation of Some Alkenyl Phosphites
Jackson, W. Roy,Moffat, Mark R.,Perlmutter, Patrick,Tasdelen, E. Elizabeth
, p. 823 - 834 (2007/10/02)
Excellent regiocontrol is achieved in the rhodium-catalysed hydroformylation of some alkenyl phosphites, and good stereocontrol is obtained in the hydroformylation of some cyclohexenyl phosphites.The stereochemical results have implications for the mechanism of these rhodium-catalysed reactions.
