68735-62-6Relevant articles and documents
An improved protocol for the synthesis of allylated isonitriles
Kazmaier, Uli,Ackermann, Stefanie
, p. 2576 - 2578 (2004)
α-Isocyanoacetates can be used as suitable nucleophiles in palladium-catalyzed allylic alkylations giving rise to α-allylated isonitriles. Best results are obtained if Cs2CO3 is used as a base to deprotonate the isonitrile, and with
Copper-catalyzed γ-selective and stereospecific direct allylic alkylation of terminal alkynes: Synthesis of skipped enynes
Makida, Yusuke,Takayama, Yurie,Ohmiya, Hirohisa,Sawamura, Masaya
supporting information, p. 5350 - 5354 (2013/06/05)
Skipping out: The title reaction using internal secondary allylic phosphates proceeded with excellent γ regioselectivity and E stereoselectivity to give skipped enynes. Enantioenriched secondary allylic phosphates proceeded with 1,3-anti stereochemistry t
New routes to ss-cycloalkylalanine derivatives using serine-derived organozinc reagents
Carrillo-Marquez, Tomas,Caggiano, Lorenzo,Jackson, Richard F. W.,Grabowska, Urszula,Rae, Alastair,Tozer, Matthew J.
, p. 4117 - 4123 (2007/10/03)
Two distinct routes to β-cycloalkylalanine derivatives have been developed. The first route employs the reaction of the iodoalanine-derived zinc-copper reagent 2 with cycloalk-l-en-3-yl phosphates, and the second uses the palladium-catalysed coupling of t
