1064-41-1Relevant academic research and scientific papers
New Reagents, XXX: Synthesis and Stability of Bis(triphenylplumbyl)methyllithium and Reactions with Alkyl Halides, Carbonyl Compounds, and Oxiranes
Kauffmann, Thomas,Rensing, Alfons
, p. 380 - 390 (2007/10/02)
Bis(triphenylplumbyl)methyllithium (2) is easily accessible by plumbyl-Li or Br-Li exchange from tris(triphenylplumbyl)methane (1b) and bromobis(triphenylplumbyl)methane (3), respectively.Due to its stability and high nucleophilicity 2 is a good reagent for the synthesis of bis(plumbyl)alkanes, -β-hydroxyalkanes, and -γ-hydroxyalkanes.
New Reagents, XXIX: Synthesis, Stability, and Preparative Applications of (Triphenylplumbyl)methyllithium
Kauffmann, Thomas,Kriegesmann, Reinhard,Rensing, Alfons,Koenig, Rolf,Steinseifer, Fritz
, p. 370 - 379 (2007/10/02)
(Triphenylplumbyl)methyllithium (2), obtained from well accessible starting compounds by iodine-Li- or plumbyl-Li exchange, is applied as a reagent for the introduction of the (triphenylplumbyl)methyl group into alkyl halides, aldehydes, ketones, oxiranes, and organoelement halides.
