106419-88-9

Basic information

• Product Name: diethyl 2-(2-(benzyloxy)benzyl)malonate
• Synonyms: diethyl 2-(2-(benzyloxy)benzyl)malonate
• CAS NO: 106419-88-9
• Molecular Weight: 356.419
• Mol File: 106419-88-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diethyl 2-(2-(benzyloxy)benzyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2-(2-(benzyloxy)benzyl)malonate(106419-88-9)
• EPA Substance Registry System: diethyl 2-(2-(benzyloxy)benzyl)malonate(106419-88-9)

Safety Data

• Hazardous Substances Data: 106419-88-9(Hazardous Substances Data)

Upstream product

• 103633-30-3 2-bromomethylphenyl benzyl ether 
• 105-53-3 diethyl malonate 
• 3381-87-1 2-benzyloxybenzyl alcohol 
• 90-01-7 salicylic alcohol 
• 100-39-0 benzyl bromide 

Downstream Products

• 881672-57-7 2,2-dimethyl-propionic acid 3-(2-benzyloxy-phenyl)-2-hydroxymethyl-propyl ester 
• 881672-51-1 2,2-dimethyl-propionic acid 2-hydroxymethyl-3-(2-hydroxy-phenyl)-propyl ester 
• 106419-92-5 2-[2-(benzyloxy)benzyl]-1,3-propanediol 

Relevant articles and documents

An aryne triggered ring-opening fluorination of cyclic thioethers with potassium fluoride

Herein, we report an aryne triggered ring-opening fluorination protocol of a great variety of saturated sulfur heterocycles. A key factor for the success is the identification of a suitable mediator. Compared to previous methods, this transition-metal free protocol employs low-cost potassium fluoride as the fluorine source. The operational simplicity and mild reaction conditions allow for the rapid synthesis of a wide range of aliphatic fluoride compounds in good yields.