214626-49-0Relevant articles and documents
Useful base promoted elaborations of oxiranyl ethers
Thurner, Angelika,Faigl, Ferenc,Toke, László,Mordini, Alessandro,Valacchi, Michela,Reginato, Gianna,Czira, Gábor
, p. 8173 - 8180 (2001)
Functionalized oxiranyl ethers can be regio- and stereoselectively converted into hydroxy oxetanes or cis-diols by treatment with organometallic bases. These two rearrangements can be conveniently carried out either using different reaction conditions sta
A new base promoted rearrangement of (E)-1-benzyloxy-2,3-epoxyalkanes
Thurner, Angelika,Faigl, Ferenc,Mordini, Alessandro,Bigi, Anna,Reginato, Gianna,Toeke, Laszlo
, p. 11597 - 11602 (1998)
(E)-1-benzyloxy-2,3-epoxyalkanes (4) underwent stereoselective rearrangement in the presence of LIDAKOR reagent and large excess of butyllithium producing (Z)-alkendiols (7) at ambident temperature. The same reaction serves anti oxetanes (6) at -75 °C whi