1079-01-2Relevant articles and documents
First synthesis of hydroxy-pinonaldehyde and hydroxy-pinonic acid, monoterpene degradation products present in atmosphere
Fache, Fabienne,Piva, Olivier,Mirabel, Philippe
, p. 2511 - 2513 (2002)
Hydroxy-pinonaldehyde and hydroxy-pinonic acid, monoterpene degradation products have been for the first time isolated by synthesis and fully characterized. The key step of the synthesis is an oxidation using the RuCl3/NaIO4 system.
Continuous-Flow Chemo and Enzymatic Synthesis of Monoterpenic Esters with Integrated Purification
Adarme, Carlos A.A.,Le?o, Raquel A.C.,de Souza, Stefania P.,Itabaiana, Ivaldo,de Souza, Rodrigo O.M.A.,Rezende, Claudia M.
, p. 39 - 46 (2018/05/22)
Monoterpenic esters are very important flavor and fragrance compounds due to their organoleptic properties. Despite their importance, many drawbacks are found for the production of monoterpenic esters. Here in we report two different approach's (chemo and enzymatic) for the continuous production of monoterpenic esters with integrated purification arriving on the desired molecules with high yields (>95%) and short reaction times.
Oxidation of α-pinene by atmospheric oxygen in the supercritical CO2-ethyl acetate system in the presence of Co(II) complexes
Anikeev,Ilina,Kurbakova,Nefedov,Volcho,Salakhutdinov
experimental part, p. 190 - 195 (2012/03/12)
The reactivity of monoterpene α-pinene in a flow reactor in the presence of cobalt catalyst in a complex supercritical solvent consisting of CO2 and ethyl acetate is studied over the temperature range of 190-320°C and a pressure range of 110-125 atm. It was found that the main isomerization products include compounds with bicyclo[2.2.1]heptane and p-menthane backbones; the reaction is accompanied by partial racemization. The formation of oxidation products is observed in the presence of air, with epoxydation rather than allylic oxidation being the predominant process at the first stage. The oxidized products (campholenic aldehyde, verbenone, pinocamphone) are shown to be formed with a high enantioselectivity; the formation of acetoxylation products is observed at temperatures above 200°C.