108295-45-0

Basic information

• Product Name: 2,2':6',2''-TERPYRIDINE-4'-CARBALDEHYDE
• Synonyms: 2,2':6',2''-TERPYRIDINE-4'-CARBALDEHYDE;4'-Formyl-2,2':6',2''-terpyridine;2,2':6',2''-Terpyridine-4'-carboxaldehyde
• CAS NO: 108295-45-0
• Molecular Formula: C₁₆H₁₁N₃O
• Molecular Weight: 261.28
• Mol File: 108295-45-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 468.2°Cat760mmHg
• Flash Point: 235.6°C
• Appearance: /
• Density: 1.236g/cm³
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• PKA: 4.24±0.22(Predicted)
• CAS DataBase Reference: 2,2':6',2''-TERPYRIDINE-4'-CARBALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2':6',2''-TERPYRIDINE-4'-CARBALDEHYDE(108295-45-0)
• EPA Substance Registry System: 2,2':6',2''-TERPYRIDINE-4'-CARBALDEHYDE(108295-45-0)

Safety Data

• Hazardous Substances Data: 108295-45-0(Hazardous Substances Data)

Usage

General Description

2,2':6',2''-Terpyridine-4'-carbaldehyde is a chemical compound with the molecular formula C20H16N4O. It is a derivative of terpyridine, which is a nitrogen-containing aromatic compound often used in coordination chemistry and materials science. 2,2':6',2''-Terpyridine-4'-carbaldehyde is commonly used in the synthesis of coordination complexes and metal-organic frameworks due to its ability to chelate with metal ions. Its aldehyde functional group also makes it useful for the preparation of various organic compounds through condensation reactions. Additionally, this compound has been investigated for its potential applications in sensors, optoelectronic devices, and supramolecular chemistry due to its unique electronic and structural properties.

Upstream product

• 72036-41-0 4'-methyl-2,2':6',2''-terpyridine 
• 17997-47-6 2-tri-n-butylstannylpyridine 
• 316800-46-1 2,6-Dibromopyridine-4-carbaldehyde 
• 223463-02-3 2,6-dibromo-4-(hydroxymethyl)pyridine 
• 90050-70-7 ethyl 2,6-dibromo-pyridine-4-carboxylate 
• 134653-69-3 4'-{[(Trifluoromethyl)sulfonyl]oxy}-2,2':6',2''-terpyridine 
• 1122-62-9 2-acetylpyridine 
• 78570-34-0 3,3-bis(methylsulfanyl)-1-pyridin-2-ylprop-2-en-1-one 
• 78570-35-1 2,6-bis(2-pyridinyl)-4-(methylthio)pyridine 
• 81874-50-2 3-(methylsulfanyl)-1,5-di(pyridin-2-yl)pent-2-ene-1,5-dione 
• 99-11-6 citrazinic acid 

Downstream Products

• 89372-90-7 5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin 
• 148332-32-5 4'-(hydroxymethyl)-2,2';6',2''-terpyridineine 
• 1435402-64-4 7-benzyl 8-tert-butyl (5R,8S)-1-{[2,6-bis-(pyridin-2-yl)pyridin-4-yl]methyl}-2,4-dioxo-3-phenyl-1,3,7-triazaspiro[4.4]nonane-7,8-dicarboxylate 
• 1435402-65-5 (5S,8S)-1-{[2,6-bis-(pyridin-2-yl)pyridin-4-yl]methyl}-2,4-dioxo-3-phenyl-1,3,7-triazaspiro[4.4]nonane-8-carboxylic acid 
• 1435402-66-6 (5R,8S)-1-{[2,6-bis-(pyridin-2-yl)pyridin-4-yl]methyl}-2,4-dioxo-3-phenyl-1,3,7-triazaspiro[4.4]nonane-8-carboxylic acid 
• 1435402-68-8 (3′S,4S,9′S,11′S)-3,3″-bis({[2,6-bis(pyridin-2-yl)pyridin-4-yl]methyl})-1,1″-diphenyldispiro[imidazolidine-4,5′-[1,7]diazatricyclo[7.3.0.03,7]-dodecane-11′,4″-imidazolidine]-2,2′,2″,5,5″,8′-hexone 
• 1435402-67-7 (5S,8S)-1-{[2,6-bis(pyridin-2-yl)pyridin-4-yl]-methyl}-2,4-dioxo-3-phenyl-7-[(prop-2-en-1-yloxy)carbonyl]-1,3,7-triazaspiro[4.4]nonane-8-carboxylic acid 
• 1435402-70-2 (3′S,4R,9′S,11′S)-3,3″-bis({[2,6-bis(pyridin-2-yl)pyridin-4-yl]methyl})-1,1″-diphenyldispiro[imidazolidine-4,5′-[1,7]diazatricyclo[7.3.0.03,7]-dodecane-11′,4″-imidazolidine]-2,2′,2″,5,5″,8′-hexone 
• 1435402-63-3 7-benzyl 8-tert-butyl (5S,8S)-1-{[2,6-bis-(pyridin-2-yl)pyridin-4-yl]methyl}-2,4-dioxo-3-phenyl-1,3,7-triazaspiro[4.4]nonane-7,8-dicarboxylate 
• 1435402-61-1 (3S,5S)-1-[(benzyloxy)carbonyl]-3-({[2,6-bis-(pyridin-2-yl)pyridin-4-yl]methyl}amino)-5-[(tert-butoxy)-carbonyl]pyrrolidine-3-carboxylic acid 
• 1148-79-4 2,2':6,2''-terpyridine 
• 58345-97-4 4'-phenyl-2,2':6',2-terpyridine 

Relevant articles and documents

Highly coupled two-component systems consisting of porphyrins attached to a rhodium(III) bis-terpyridine complex

A 2,2′,6′,2″-terpyridine (terpy) ligand bearing a porphyrin unit at its 4′ position has been made as well as the corresponding rhodium(III) bis-terpy complex. The porphyrin site can be metallated by zinc(II).

An efficient and easy route to trimethyl derivatives of 2,2':6',2''-terpyridine

By using the Stille coupling reaction, trimethyl derivatives of 2,2':6',2''-terpyridine have been prepared in good yields.

Photoinduced electron- and energy-transfer processes occurring within porphyrin-metal-bisterpyridyl conjugates

Photophysical properties have been measured for zinc and free-base porphyrins covalently linked to ruthenium-(II) or rhodium(III) bisterpyridyl complexes using ultrafast transient absorption spectroscopy. The appended metal complex quenches porphyrin fluo