72036-41-0

Basic information

• Product Name: 4'-METHYL-2,2':6',2''-TERPYRIDINE
• Synonyms: 4'-METHYL-2,2':6',2''-TERPYRIDINE
• CAS NO: 72036-41-0
• Molecular Formula: C₁₆H₁₃N₃
• Molecular Weight: 247.29
• Mol File: 72036-41-0.mol

Chemical Properties

• Boiling Point: 401.464 °C at 760 mmHg
• Flash Point: 178.511 °C
• Appearance: /
• Density: 1.145 g/cm³
• CAS DataBase Reference: 4'-METHYL-2,2':6',2''-TERPYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-METHYL-2,2':6',2''-TERPYRIDINE(72036-41-0)
• EPA Substance Registry System: 4'-METHYL-2,2':6',2''-TERPYRIDINE(72036-41-0)

Safety Data

• Hazardous Substances Data: 72036-41-0(Hazardous Substances Data)

Usage

Uses

Used in Optical and Electronic Devices:
4'-Methyl-2,2':6',2''-terpyridine is used as a component in the development of light-emitting diodes and photovoltaic cells due to its potential to enhance the performance and efficiency of these devices.
Used in Coordination Polymers and Metal-Organic Frameworks:
4'-METHYL-2,2':6',2''-TERPYRIDINE is utilized as a building block for the synthesis of coordination polymers and metal-organic frameworks, which have potential applications in gas storage, catalysis, and sensing.
Used in Fluorescent Probes for Metal Ion Detection:
4'-Methyl-2,2':6',2''-terpyridine serves as a fluorescent probe for detecting metal ions in biological and environmental samples, offering a sensitive and selective method for metal ion analysis.
Used in Chemical and Materials Science Research:
4'-METHYL-2,2':6',2''-TERPYRIDINE is employed as a subject of study in chemical and materials science research to explore its unique structure, coordination behavior, and potential applications in various fields.

Upstream product

• 100-70-9 2-Cyanopyridine 
• 41792-83-0 Li₂(TMM)(TMEDA)2 
• 594-27-4 tetramethylstannane 
• 134653-69-3 4'-{[(Trifluoromethyl)sulfonyl]oxy}-2,2':6',2''-terpyridine 
• 4664-16-8 4-methyl-2,6-dihydroxypyridine 
• 19013-37-7 dimethyl 3-methylglutarate 
• 626-51-7 3-methyl glutaric acid 
• 81874-50-2 3-(methylsulfanyl)-1,5-di(pyridin-2-yl)pent-2-ene-1,5-dione 
• 119715-60-5 (E)-1-(pyridine-2-yl)-N-(pyridine-2-ylmethylene)methaneamine 
• 78570-34-0 3,3-bis(methylsulfanyl)-1-pyridin-2-ylprop-2-en-1-one 
• 1122-62-9 2-acetylpyridine 
• 73112-16-0 2,6-Dibromo-4-methylpyridine 
• 17997-47-6 2-tri-n-butylstannylpyridine 
• 207804-48-6 3-Methyl-1,5-di-pyridin-2-yl-pentane-1,5-dione 

Downstream Products

• 152793-28-7 4'-(2'''-Phenylethyl)-2,2':6',2''-terpyridine 
• 167026-72-4 4'-Hentriacontyl-2,2':6',2''-terpyridine 
• 152793-37-8 4'-<2'''-(4''''-Nitrophenyl)ethyl>-2,2':6',2''-terpyridine-6,6''-dicarbonitrile 
• 152793-33-4 4'-<2'''-(4''''-Nitrophenyl)ethyl>-2,2':6',2''-terpyridine N,N''-dioxide 
• 152793-29-8 4'-<2'''-(4''''-Nitrophenyl)ethyl>-2,2':6',2''-terpyridine 
• 208597-43-7 4'-((diphenylphosphinoyl)methylene)-2,2':6',2''-terpyridine 
• 536696-95-4 4'-[bis-(diphenyl-phosphinoyl)-methyl]-[2,2';6',2'']terpyridine 
• 288103-61-7 4'-[bis(diphenylphosphino)methane]-2,2':6',2''-terpyridine 
• 288103-62-8 4'-[(Diphenylphosphanyl)-methyl]-[2,2';6',2'']terpyridine 
• 108295-45-0 4′-formyl-2,2′:6′2″-terpyridine 

Relevant articles and documents

Compound for molecular electronic device having thiol anchoring group, method of synthesizing the compound, and molecular electronic device having molecular active layer obtained from the compound

Provided are a compound for a molecular electronic device which includes a terpyridine-ruthenium organic metal compound including a thiol anchoring group of the formula below, a method of synthesizing the compound and a molecular electronic device including a molecular active layer obtained from the compound. In the formula, R1 and R2 are each a thioacetyl group or a hydrogen atom, at least one of R1 and R2 is a thioacetyl group, and m and n are each integers from 0 to 20. The molecular active layer, which is formed by self-assembling the compound on an electrode surface, composes a switching element and a memory element.

An efficient and easy route to trimethyl derivatives of 2,2':6',2''-terpyridine

By using the Stille coupling reaction, trimethyl derivatives of 2,2':6',2''-terpyridine have been prepared in good yields.

Bucky ligands: Synthesis, Ruthenium(II) complexes, and electrochemical properties

The novel tridentate 2,2':6',2-terpyridine ligand (1) in which the metal-binding domain is directly attached to a methanofullerene C60 unit was incorporated into ruthenium-based diads and triads that may undergo photoinduced charge s

Amphiphilic Terpyridine Complexes of Ruthenium and Rhodium displaying Lyotropic Mesomorphism

New 4'-alkyl-substituted 2,2':6',2''-terpyridine (4'R-terpy) compounds have been synthesised from 4'-methyl-2,2':6',2''-terpyridine and an appropriate 1-bromoalkane and complexed with ruthenium and rhodium to yield new bis(terpyridine) complexes (2+) (R = C19H39 or C31H63) and (3+) (R = C19H39) as chloride and hexafluorophosphate salts.These complexes are amphiphilic being structurally related to surfactant tris(bipyridine)ruthenium complexes.Both ruthenium and rhodium complexes with R = C19H39 and chloride counter ions show lyotropic mesomorphism in water, and the ruthenium complex with R = C31H63 shows mesophase formation in ethylene glycol.

Photoinduced electron- and energy-transfer processes occurring within porphyrin-metal-bisterpyridyl conjugates

Photophysical properties have been measured for zinc and free-base porphyrins covalently linked to ruthenium-(II) or rhodium(III) bisterpyridyl complexes using ultrafast transient absorption spectroscopy. The appended metal complex quenches porphyrin fluo

Highly coupled two-component systems consisting of porphyrins attached to a rhodium(III) bis-terpyridine complex

A 2,2′,6′,2″-terpyridine (terpy) ligand bearing a porphyrin unit at its 4′ position has been made as well as the corresponding rhodium(III) bis-terpy complex. The porphyrin site can be metallated by zinc(II).

A NEW SYNTHESIS OF PIPERIDINES AND PYRIDINES: ANNULATION OF 2-AZAALLYL ANIONS

A one-pot approach to 6-membered heterocyclic rings combines two 1,3-dipole equivalents: 2-azaallyl anions(2) and iodosilane 3.The resulting cis-2,6-disubstituted 4-methylenepiperidines are converted in high yield to 2,4,6-trisubstituted pyridines (6) by oxidation with mercuric acetate in acetic acid.

4-Vinyl-, 6-Vinyl-, and 4'-Vinyl-2,2':6',2''-terpyridinyl Ligands: Their Synthesis and the Electrochemistry of Their Transition-Metal Coordination Complexes

4'-Vinyl-2,2':6',2''-terpyridinyl was conveniently prepared from 2-acetylpyridine via α-oxoketene dithioacetal methodology, the intermediate 4'-(methylthio)-2,2':6',2''-terpyridinyl being converted into the corresponding 4'-methyl derivative with methylma