108415-83-4Relevant articles and documents
Oxone-Mediated Oxidation of Vinyl Selenides in Water
Palomba, Martina,Trappetti, Francesco,Bagnoli, Luana,Santi, Claudio,Marini, Francesca
, p. 3914 - 3919 (2018/07/31)
A simple and practical procedure for the oxidation of vinyl selenides into the corresponding selenones using Oxone in water at 60 °C has been reported. Structurally diverse phenyl vinyl selenones were oxidized under heterogeneous conditions without organi
COMPETITION BETWEEN VINYLIC SUBSTITUTION AND CONJUGATE ADDITION IN THE REACTIONS OF VINYL SELENOXIDES AND VINYL SELENONES WITH NUCLEOPHILES IN DMF
Tiecco, Marcello,Chianelli, Donatella,Testaferri, Lorenzo,Tingoli, Marco,Bartoli, Donatella
, p. 4889 - 4896 (2007/10/02)
Vinyl selenoxides and vinyl selenones present a different reactivity towards thiolate or alkoxide anions in DMF.In the case of selenoxides the addition of the nucleophiles regioselectively occurs at the α-carbon leading to the formation of the vinylic sub