1089298-03-2Relevant articles and documents
A remarkably simple α-oximation of ketones to 1,2-dione monooximes using the chlorotrimethylsilane-isoamyl nitrite combination
Mohammed, Abdulkarim H.A.,Nagendrappa, Gopalpur
, p. 2753 - 2755 (2003)
Ketones undergo α-oximation by NOCl formed in situ from Me3SiCl and isoamyl nitrite, either in solution or under solvent-free conditions, to produce 1,2-dione monooximes in excellent yields. The oximation is regiospecific in appropriate cases.
Palladium-catalyzed highly regioselective oxidative homocoupling of 1,2,3-triazole N-oxides
Peng, Xiangjun,Huang, Panpan,Jiang, Lili,Zhu, Jiayi,Liu, Liangxian
supporting information, p. 5223 - 5226 (2016/11/11)
A convenient and highly regioselective palladium-catalyzed direct C–H homocoupling of 1,2,3-triazole N-oxides was developed in the presence of silver carbonate and 1,10-phenanthroline. This protocol provides a straightforward and operationally simple rout
A new cyclic ligand and complexes of its open-chain tautomer with Co(III) and Ni(II) ions: Synthesis, characterization and thermal properties
Sirikci,Genckal, H. Mutlu,Irez
, p. 1139 - 1145 (2013/07/11)
A new ligand, 2-(p-tolyl)-1,2,3,4-tetrahydroquinazoline-2 -carbaldehyde oxime, was synthesized from a condensation reaction of oxo-p-tolyl-acetaldehyde oxime with 2-aminobenzyl- amine and then amine-imine-oxime complexes of this compound that formed with Co(III) and Ni(II) ions were obtained. All structures were characterized by spectral methods, elemental analysis, magnetic susceptibility, molar conductivity, and thermal analyses. The results that were obtained show that the cyclic ligand, HL, undergoes a ring-opening reaction upon complexation with metal ions. The Co(III) and Ni(II) complexes have a metal-ligand ratio of 1:2 and the imine ligand coordinates through the amine, imine, and oxime groups nitrogen atoms with metal ions. Copyright Taylor & Francis Group, LLC.