109491-07-8

Upstream product

• 931-59-9 benzenesulfenyl chloride 
• 627-41-8 propargyl alcohol methyl ether 
• 882-33-7 diphenyldisulfane 
• 98-09-9 benzenesulfonyl chloride 

Downstream Products

• 109458-93-7 (4-Chloro-2-methoxymethyl-5,5-dimethyl-cyclopent-1-enylsulfanyl)-benzene 
• 1056280-14-8 C₁₆H₁₆OS 
• 1056280-20-6 C₁₇H₁₈OS 
• 879416-73-6 Tributyl-((E)-3-methoxy-1-phenylsulfanyl-propenyl)-stannane 
• 1179540-11-4 1-phenylthio-2-(p-methylphenyl)thio-3-methoxypropene 

Relevant academic research and scientific papers

Synthesis and cytotoxic properties of a series of bicyclo[3.2.1]octane α-methylene ketones

The 8-chlorobicyclo[3.2.1]oct-6-ene 3 has been prepared by a [3+2] cycloaddition route, and converted to the bicyclic α-methylene ketones 6 and 8-12, some of which showed cytotoxic properties.

CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides

A CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides/PPh3 has been explored. This reaction proceeded smoothly through an alkyl/aryl radical (generated from organometallics) under mild conditions and produced the desired sulfide products in excellent yields.

Stereoselective synthesis of (Z)-1,2-diarylthio-1-alkene via the reaction of diaryl disulfides with terminal alkynes catalyzed by cesium hydroxide

In the presence of a catalytic amount of cesium hydroxide under a nitrogen atmosphere, terminal alkynes reacted with diaryl disulfides at room temperature in dimethylformamide to give almost exclusively (Z)-1,2-diarylthio-1-alkene in good yields, but unde