1-phenylsulphenyl-2-methoxymethylethyne

Base Information

• Chemical Name: 1-phenylsulphenyl-2-methoxymethylethyne
• CAS No.: 109491-07-8
• Molecular Formula: C₁₀H₁₀OS
• Molecular Weight: 178.255
• Mol file: 109491-07-8.mol

Synonyms:1-phenylsulphenyl-2-methoxymethylethyne

Chemical Property of 1-phenylsulphenyl-2-methoxymethylethyne

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenylsulphenyl-2-methoxymethylethyne

There total 3 articles about 1-phenylsulphenyl-2-methoxymethylethyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

benzenesulfenyl chloride (931-59-9) + propargyl alcohol methyl ether (627-41-8) → 1-phenylsulphenyl-2-methoxymethylethyne (109491-07-8)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at -78 ℃;

DOI:10.1016/S0040-4039(01)00235-0

Reference yield: 76.0%

benzenesulfonyl chloride (98-09-9) + C4H5BrOZn → 1-phenylsulphenyl-2-methoxymethylethyne (109491-07-8)

Guidance literature:

benzenesulfonyl chloride; With [2,2]bipyridinyl; copper(l) iodide; triphenylphosphine; In tetrahydrofuran; N,N-dimethyl-formamide; Inert atmosphere;

C₄H₅BrOZn; at 20 ℃; Inert atmosphere;

DOI:10.1039/c6ra27201k

Reference yield:

diphenyldisulfane (882-33-7) + propargyl alcohol methyl ether (627-41-8) → (Z)-(3-methoxyprop-1-ene-1,2-diyl)bis(phenylsulfane) + 1-phenylsulphenyl-2-methoxymethylethyne (109491-07-8)

Guidance literature:

With cesium hydroxide; air; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1080/00397910802654831

upstream raw materials:

benzenesulfenyl chloride

propargyl alcohol methyl ether

diphenyldisulfane

benzenesulfonyl chloride

Downstream raw materials:

1-phenylthio-2-(p-methylphenyl)thio-3-methoxypropene

(Z)-1-benzoyl-1-phenylthio-3-methoxypropene

(Z)-1-(4-methylbenzoyl)-1-phenylthio-3-methoxypropene

(Z)-1-(4-chlorobenzoyl)-1-phenylthio-3-methoxypropene