109559-47-9

Usage

Uses

Used in Coordination Chemistry:
1,10-Phenanthroline, 2-phenylis used as a versatile ligand in coordination chemistry for the synthesis of metal complexes. Its ability to form stable complexes with metal ions makes it a valuable compound in this field.
Used in Analytical Chemistry:
As a chelating agent, 1,10-Phenanthroline, 2-phenylis used in analytical chemistry for the detection and quantification of metal ions. Its interaction with metal ions allows for accurate measurements and analysis.
Used in Biology and Medicine:
1,10-Phenanthroline, 2-phenylis used as a fluorescent probe for metal ions in biological and medical applications. Its fluorescence properties enable the detection and monitoring of metal ion concentrations in various biological systems.
Used in Environmental Science:
In environmental science, 1,10-Phenanthroline, 2-phenylis used for the detection and analysis of metal ion contamination in various environmental samples, such as water, soil, and air.
Used in Materials Science:
1,10-Phenanthroline, 2-phenylis also utilized in materials science for the development of new materials with specific properties, such as metal-organic frameworks (MOFs) and coordination polymers, which can have applications in gas storage, catalysis, and drug delivery.

Upstream product

• 116529-78-3 2-phenylquinolin-8-ylamine 
• 66-71-7 1,10-Phenanthroline 
• 591-51-5 phenyllithium 
• 7471-63-8 8-nitro-7-methylquinoline 
• 176853-39-7 7-<β-trans-(N,N-dimethylamino)ethenyl>-8-nitroquinoline 
• 101327-87-1 8-nitro-7-quinolinecarboxaldehyde 
• 98-86-2 acetophenone 
• 158753-17-4 8-amino-7-quinolinecarbaldehyde 

Downstream Products

• 160488-06-2 2-phenyl-9-p-tolyl-1,10-phenanthroline 
• 929548-03-8 C₂₉H₂₈N₂ 
• 929548-02-7 C₂₉H₂₈N₂ 
• 929548-01-6 C₂₉H₂₈N₂ 
• 929548-04-9 C₃₁H₂₄N₂ 
• 929548-00-5 C₂₆H₂₂N₂ 
• 160488-08-4 4-(9-phenyl-1,10-phenanthrolin-2-yl)benzaldehyde 
• 160488-09-5 4-(9-phenyl-1,10-phenanthrolin-2-yl)benzoic acid 
• 160488-07-3 2-(4-dibromomethylphenyl)-9-phenyl-1,10-phenanthroline 
• 160488-05-1 N-(6-methylpyridin-2-yl)-4-(9-phenyl-1,10-phenanthrolin-2-yl)benzamide 
• 1032154-55-4 C₁₈H₂₀N₂ 
• 1290058-34-2 [iridium(III)(2-phenylpyridine-1H)2(2-phenyl-1,10-phenanthroline)](PF₆) 
• 889663-70-1 bis(2-phenyl-1,10-phenanthroline)copper(I) hexafluorophosphate 
• 1263175-14-9 2-isopropyl-9-phenyl-[1,10]phenanthroline 

Relevant academic research and scientific papers

A self-assembling receptor for dicarboxylic acids

In this paper we describe a simple binding subunit that self-assembles in the presence of metal ions to form a receptor for dicarboxylic acids. The resultant binding site is chiral and strong complexation to dicarboxylic acids in CDCl3 can be d

Intriguing C-H?Cu interactions in bis-(phenanthroline)Cu(i) redox mediators for dye-sensitized solar cells

We have synthesized and characterized a series of bis-(phenanthroline)Cu(i) complexes of interest as redox mediators for dye-sensitized solar cells. This study led to the discovery of intriguing anagostic interactions between the hydrogen atom and the copper center as evidenced by X-ray diffraction studies on a single crystal. Remarkably, an anagostic interaction was found between a H atom of a methyl group and a copper site.

Nickel(II)-Catalyzed Asymmetric Michael Addition of Oxindoles with Modified N,N,O-Tridentate Chiral Phenanthroline Ligands

Nickel(II)-catalyzed enantioselective Michael addition of N-Boc-oxindole derivatives with methyl vinyl ketone was demonstrated to give the corresponding adducts having chiral all-carbon quaternary centers with up to 87% ee in the presence of axially chira

NOVEL COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE

A compound is represented by a formula (1) below. In the formula (1), X 1 to X 8 each independently represent a carbon atom to be bonded to a group represented by a formula (20) below, CR X or a nitrogen atom. At least one of X 1 to X 8 is a carbon atom to be bonded to the group represented by the formula (2). R X is independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, and the like.

A rapid synthesis of asymmetric alkyl- and aryl-2,9-disubstitued 1,10-phenanthrolines

The finding that alkyl- and aryllithium reagents add almost instantly to the N-C2/C9 bond of 1,10-phenanthrolines led us to the development of a reaction scheme where the C2 and C9 positions of 1,10-phenanthroline can be functionalized by two different al

Introduction of benzo[h]quinoline and 1,10-phenanthroline subunits by friedl?nder methodology

An improved preparation of 8-amino-7-quinolinecarbaldehyde has been developed. The methyl group of 7-methyl-8-nitroquinoline may be oxidized to an aldehyde by treatment first with dimethylformamide dimethyl acetal followed by sodium periodate. Reduction with iron provides the amino aldehyde. An analogous sequence affords 1-amino-2-naphthalenecarbaldehyde. Friedl?nder condensation of the quinoline derivative with a series of acetylaromatics provides the corresponding 2-aryl-1,10-phenanthrolines. Condensation of either amino aldehyde with 1,3-diacetylbenzene or 2,6-diacetylpyridine provides the expected Friedl?nder product. Similar chemistry is described for reactions of the amino aldehydes with 1,4-diacetylbenzene, 4,4′-diacetylbiphenyl, 1,5-diacetylanthracene, 1,2,3,4,5,6,7,8-octahydroacridine-1,8-dione, and tetracyclo-[6.3.0.0.4,1105,9]undecane-2,7-dione (TCU-2,7-dione).

Self-assembling, chromogenic receptors for the recognition of dicarboxylic acids

The synthesis of ligands (2,9-disubstituted phenanthrolines) bearing one or two acylaminopyridine binding sites, compounds 1 and 2 respectively, is described. Each ligand can assemble on a Cu(I) template, forming two different receptors for dicarboxylic a