109704-79-2

Basic information

• Product Name: N^b-benzyl-21-hydroxy-D-seco-Ψ-vincadifformine
• CAS NO: 109704-79-2
• Molecular Weight: 446.59
• Mol File: 109704-79-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N^b-benzyl-21-hydroxy-D-seco-Ψ-vincadifformine(CAS DataBase Reference)
• NIST Chemistry Reference: N^b-benzyl-21-hydroxy-D-seco-Ψ-vincadifformine(109704-79-2)
• EPA Substance Registry System: N^b-benzyl-21-hydroxy-D-seco-Ψ-vincadifformine(109704-79-2)

Safety Data

• Hazardous Substances Data: 109704-79-2(Hazardous Substances Data)

Upstream product

• 1575-73-1 2-ethyl-pent-4-enoic acid 
• 121074-25-7 (4R,5S)-3-((R)-2-Ethyl-pent-4-enoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 121074-26-8 tert-Butyl-((R)-2-ethyl-pent-4-enyloxy)-dimethyl-silane 
• 121074-27-9 (R)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-hexan-1-ol 
• 85622-00-0 2-Ethyl-pent-4-enoyl chloride 
• 89790-39-6 (2R)-2-Ethyl-4-penten-1-ol 
• 42998-02-7 methyl 2-ethyl-4-pentenoate 
• 121074-31-5 N^b-benzyl-21-<(tert-butyldimethylsilyl)oxy>-D-seco-Ψ-vincadifformine 
• 121074-25-7 (4R,5S)-3-[(2S)-1-oxo-2-ethyl-4-pentenyl]-4-methyl-5-phenyl-2-oxazolidinone 
• 121074-24-6 (S)-4-ethyl-5-<(tert-butyldimethylsilyl)oxy>pentanal 
• 121074-22-4 tert-Butyl-((S)-2-ethyl-pent-4-enyloxy)-dimethyl-silane 
• 121074-23-5 (S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-hexan-1-ol 
• 121074-21-3 (2S)-2-ethyl-4-penten-1-ol 
• 121074-31-5 N^b-benzyl-21-<(tert-butyldimethylsilyl)oxy>-D-seco-Ψ-vincadifformine 

Downstream Products

• 28808-73-3 14'-epi-20'-deoxyvincovaline 
• 57194-39-5 C₄₆H₅₈N₄O₈ 
• 109704-82-7 C₆₀H₇₂N₄O₁₁S 
• 109704-82-7 C₆₀H₇₂N₄O₁₁S 
• 109704-82-7 C₆₀H₇₂N₄O₁₁S 
• 109704-82-7 C₆₀H₇₂N₄O₁₁S 
• 109704-81-6 C₆₀H₇₀N₄O₁₁S 
• 109735-39-9 (3aS,4R,11bR)-3-Benzyl-6-chloro-4-[(S)-2-(toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,6-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 
• 109735-39-9 (3aS,4R,11bR)-3-Benzyl-6-chloro-4-[(R)-2-(toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,6-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 
• 121074-32-6 (R)-4-[(R)-2-(Toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 
• 121074-32-6 (R)-4-[(S)-2-(Toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 
• 3327-43-3 C₂₁H₂₈N₂O₂ 
• 3327-43-3 C₂₁H₂₈N₂O₂ 
• 3327-43-3 C₂₁H₂₈N₂O₂ 

Relevant articles and documents

Syntheses of 20'-Deoxyvinblastine, 20'-Deoxyleurosidine, 20'-Deoxyvincovaline, 20'-epi-20'-Deoxyvincovaline, and 20'-Deoxyvincristine and Its 20'-Epimer through Racemic and Enantioselectively Generated Intermediates. New Syntheses of D/E-cis- and -trans-Ψ

Vindoline (20), on reaction with chloro imine derivatives of the D-seco-D/E-trans-Ψ- and -20-epi-Ψ-vincadifformines 18 and 19, followed by cyclization and debenzylation steps, provided the natural products 20'-deoxyvinblastine (4) and 20'-deoxyleurosidine